Measurement evidence
A Light-Responsive Metal–Organic Framework Hybrid Membrane with High On/Off Photoswitchable Proton Conductivity · Liang H.-Q., Guo Y., Shi Y. et al. · Angewandte Chemie - International Edition · 2020 · 7732-7737
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
SSP@ZIF-8-10% membrane · Thin Film
Arrhenius plots of ZIF-8 and SSP@ZIF-8 membranes with different SSP contents under 95% RH.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| SSP@ZIF-8 activation-energy range | 0.4-1.1 eV | — | — | Text Range | 3 · Results and discussion · Figure 3c |
| ZIF-8 activation energy under 95% RH | 0.43 eV | — | — | Text Exact Reported | 3 · Results and discussion · Figure 3c |
SSP@ZIF-8-10% membrane · Thin Film
Proton conductivity of SSP@ZIF-8-10% under 55-95% RH at 25 degC in the dark.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| SSP@ZIF-8-10% conductivity at 55% RH and 25 degC | 5.5 x 10-7 S cm-1 | — | — | Text Rounded Reported | 3 · Results and discussion · Figure 3b |
| SSP@ZIF-8-10% conductivity at 95% RH and 25 degC | 1.0 x 10-4 S cm-1 | — | — | Text Rounded Reported | 3 · Results and discussion · Figure 3b |
SSP@ZIF-8-10% membrane with Ag electrodes for impedance and LED switching · Electrode
Light/dark proton conductivity of SSP@ZIF-8-10% at 25-75 degC and 95% RH; visible-light source was a 150 W Xe lamp with 400 nm filter at 100 mW cm-2.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| SSP@ZIF-8-10% on-mode conductivity at 25 degC from Table 1 | 1.7 x 10-4 S cm-1 | — | — | Table Rounded Reported | 4 · Table 1 · Table 1 |
| SSP@ZIF-8-10% conductivity at 25 degC in dark | (1.0 +/- 0.6) x 10-4 S cm-1 | — | +/- 0.6 x 10-4 S cm-1 | Text Rounded Reported | 4 · Results and discussion · Figure 3d |
| SSP@ZIF-8-10% conductivity at 25 degC under visible light | (3.1 +/- 0.8) x 10-7 S cm-1 | — | +/- 0.8 x 10-7 S cm-1 | Text Rounded Reported | 4 · Results and discussion · Figure 3d |
| SSP@ZIF-8-10% on-mode conductivity at 75 degC from Table 1 | 0.043 S cm-1 | — | — | Table Exact Reported | 4 · Table 1 · Table 1 |
| SSP@ZIF-8-10% conductivity at 75 degC in darkMarked as a best value within this paper | 0.05 +/- 0.01 S cm-1 | — | +/- 0.01 S cm-1 | Text Rounded Reported | 3-4 · Abstract; Results and discussion · Figure 3d |
| SSP@ZIF-8-10% conductivity at 75 degC under visible light | (1.8 +/- 0.2) x 10-6 S cm-1 | — | +/- 0.2 x 10-6 S cm-1 | Text Rounded Reported | 4 · Results and discussion · Figure 3d |
| SSP@ZIF-8-10% on/off ratio at 25 degC from Table 1 | 200 | — | — | Table Exact Reported | 4 · Table 1 · Table 1 |
| SSP@ZIF-8-10% on/off ratio at 25 degC | about 300 | — | — | Text Approximate | 4 · Results and discussion · Figure 3d |
| SSP@ZIF-8-10% on/off ratio at 75 degCMarked as a best value within this paper | 2.8 x 10^4 | — | — | Text Rounded Reported | 4 · Results and discussion · Figure 3d; Table 1 |
SSP@ZIF-8-10% membrane · Thin Film
Proton conductivity of ZIF-8 and SSP@ZIF-8 membranes with different SSP contents at 25 degC and 95% RH in the dark.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| SSP@ZIF-8-10% optimum proton conductivity at 25 degC and 95% RH | (1.0 +/- 0.6) x 10-4 S cm-1 | — | +/- 0.6 x 10-4 S cm-1 | Text Rounded Reported | 3 · Results and discussion · Figure 3a |
| SSP@ZIF-8-1% proton conductivity at 25 degC and 95% RH | approximately 5 x 10-6 S cm-1 from Figure 3a | — | — | Figure Axis Approximate | 3 · Figure caption · Figure 3a |
| SSP@ZIF-8-20% proton conductivity at 25 degC and 95% RH | approximately 1.5 x 10-5 S cm-1 from Figure 3a | — | — | Figure Axis Approximate | 3 · Results and discussion · Figure 3a; Figure S2c,f |
| SSP@ZIF-8-5% proton conductivity at 25 degC and 95% RH | approximately 2 x 10-5 S cm-1 from Figure 3a | — | — | Figure Axis Approximate | 3 · Figure caption · Figure 3a |
| Pristine ZIF-8 proton conductivity at 25 degC and 95% RH | approximately 1 x 10-6 S cm-1 from Figure 3a | — | — | Figure Axis Approximate | 3 · Results and discussion · Figure 3a |
SSP@ZIF-8-10% membrane with Ag electrodes for impedance and LED switching · Electrode
Membrane irradiated by visible light for 5 s for on-to-off transformation, then stored in dark for 5 min for off-to-on transformation; repeated 100 times.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Reversible switching cycle count | 100 cycles without significant decrease | — | — | Text Exact Reported | 4 · Results and discussion · Figure 3e |
| On/off ratio maintained after cycling at 55 degC | around 1200 | — | — | Text Approximate | 4 · Results and discussion · Figure 3e |
| Off-mode to on-mode dark recovery time | 5 min | — | — | Text Exact Reported | 4 · Results and discussion · Figure 3e |
| On-mode to off-mode response time under visible lightMarked as a best value within this paper | within 5 seconds; illumination time 5 s | — | — | Text Rounded Reported | 4 · Results and discussion; Table 1 · Figure 3e; Table 1 |
ZIF-8 membrane after external SSP immersion · Thin Film
Pristine ZIF-8 and ZIF-8 after 12 h immersion in 0.03 wt% SSP aqueous solution compared at different temperatures.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ZIF-8 after SSP immersion conductivity at 25 degC | approximately 2.5 x 10-6 S cm-1 from Figure S7 | — | — | Figure Axis Approximate | 7 · Figure captions · Figure S7 |
| ZIF-8 after SSP immersion conductivity at 75 degC | approximately 2.1 x 10-5 S cm-1 from Figure S7 | — | — | Figure Axis Approximate | 7 · Figure captions · Figure S7 |
| Effect of external SSP immersion on ZIF-8 conductivity | No improvement in proton conductivity was observed | — | — | Text Qualitative | 2 · Results and discussion · Figure S7 |