Electrochemistry Application — Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance

12 measurement groups · 35 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

Voltammetry

Synthesised In10 MOF powder · Powder

Ag/AgCl reference electrode, Pt plate working electrode, Pt slice counter electrode, 0.1 M Bu4NPF6 in chlorobenzene, 50 mV/s, Fc/Fc+ internal standard.

Geometry: three-electrode cell
Context: Pristine In10 used to calculate frontier orbital levels.
Measurement source: 2 · 2.3. Measurements and characterizations · Fig. 1a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
In10 HOMO energy level	-5.06 eV	-5.06 eV	—	Text Exact Reported	2 · 3. Results and discussion · Fig. 1a,b
In10 LUMO energy level	-2.13 eV	-2.13 eV	—	Text Exact Reported	2 · 3. Results and discussion · Fig. 1a,b
In10 optical gap used for energy-level calculation	2.97 eV	2.97 eV	—	Text Exact Reported	2 · 3. Results and discussion · Fig. 1a
Spiro-OMeTAD HOMO energy level shown for alignment	-5.22 eV	-5.22 eV	—	Figure Axis Rounded Reported	3 · 3. Results and discussion · Fig. 1b
Spiro-OMeTAD LUMO energy level shown for alignment	-2.21 eV	-2.21 eV	—	Figure Axis Rounded Reported	3 · 3. Results and discussion · Fig. 1b

Dark J-V, electrochemical impedance spectroscopy (EIS), IPCE and surface photovoltage spectroscopy

Photoresponse and photoelectrochemistry Impedance spectroscopy

PSC with HTM/In10-4 · Electrode

Dark J-V and EIS from optoelectronic measurement system/gamry workstation; IPCE with 1/4 monochromator and 300 W xenon lamp; SPS with 500 W xenon lamp, double-prism monochromator and lock-in amplifier.

Geometry: PSC series; row assigned to best HTM/In10-4 sample
Context: HTM control and HTM/In10 PSCs.
Measurement source: 5 · 3. Results and discussion · Fig. 4b,c; Fig. 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Dark J-V current density trend	HTM/In10-2 and HTM/In10-4 have lower dark current than HTM; HTM/In10-6 dark current increases versus HTM/In10-4	—	—	Text Qualitative	5 · 3. Results and discussion · Fig. 4b
EIS charge transport/recombination trend	from 2 to 4 mg/mL In10 charge transport resistance falls and recombination resistance rises; 6 mg/mL reverses this trend	—	—	Text Qualitative	5 · 3. Results and discussion · Fig. 4c
IPCE enhancement wavelength range	obvious enhancement from 300 nm to 800 nm compared with HTM based PSC	—	—	Text Range	5 · 3. Results and discussion · Fig. 5a
Surface photovoltage response	HTM/In10 PSCs show enhanced SPS signal response versus HTM; trend follows IPCE	—	—	Text Qualitative	5 · 3. Results and discussion · Fig. 5b

Electrochemical impedance spectroscopy numerical fit table

Impedance spectroscopy

PSC with HTM control · Electrode

EIS numerical values read from SI Table S2.

Geometry: PSC with no-In10 HTM control
Context: Control PSC EIS.
Measurement source: S-5 · Supporting Information · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HTM PSC Rs	51.1 ohm	51.1 ohm	—	SI Table Exact Reported	S-5 · Supporting Information · Table S2
HTM PSC Rsh	2953.0 ohm	2953 ohm	—	SI Table Exact Reported	S-5 · Supporting Information · Table S2

Electrochemical impedance spectroscopy numerical fit table

Impedance spectroscopy

PSC with HTM/In10-2 · Electrode

EIS numerical values read from SI Table S2.

Geometry: PSC with HTM/In10-2
Context: 2 mg mL-1 In10 PSC EIS.
Measurement source: S-5 · Supporting Information · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HTM/In10-2 PSC Rs	25.0 ohm	25 ohm	—	SI Table Exact Reported	S-5 · Supporting Information · Table S2
HTM/In10-2 PSC Rsh	8968.3 ohm	8968.3 ohm	—	SI Table Exact Reported	S-5 · Supporting Information · Table S2

Electrochemical impedance spectroscopy numerical fit table

Impedance spectroscopy

PSC with HTM/In10-4 · Electrode

EIS numerical values read from SI Table S2.

Geometry: PSC with HTM/In10-4
Context: Best 4 mg mL-1 In10 PSC EIS.
Measurement source: S-5 · Supporting Information · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HTM/In10-4 PSC RsMarked as a best value within this paper	22.9 ohm	22.9 ohm	—	SI Table Exact Reported	S-5 · Supporting Information · Table S2
HTM/In10-4 PSC RshMarked as a best value within this paper	12830.9 ohm	12830.9 ohm	—	SI Table Exact Reported	S-5 · Supporting Information · Table S2

Electrochemical impedance spectroscopy numerical fit table

Impedance spectroscopy

PSC with HTM/In10-6 · Electrode

EIS numerical values read from SI Table S2, with the HTM/In10-6 row continuing onto rendered page S-6.

Geometry: PSC with HTM/In10-6
Context: 6 mg mL-1 In10 PSC EIS.
Measurement source: S-6 · Supporting Information · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HTM/In10-6 PSC Rs	30.1 ohm	30.1 ohm	—	SI Table Exact Reported	S-6 · Supporting Information · Table S2
HTM/In10-6 PSC Rsh	11610.2 ohm	11610.2 ohm	—	SI Table Exact Reported	S-6 · Supporting Information · Table S2

Photocurrent density-voltage (J-V)

Photoresponse and photoelectrochemistry

PSC with HTM control · Electrode

J-V measured under calibrated 450 W xenon lamp; cell area 0.06 cm2 determined by metal aperture.

Geometry: 0.06 cm2 perovskite solar cell
Context: PSC with no-In10 HTM control.
Measurement source: 2 · 2.3. Measurements and characterizations · Fig. 4a; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HTM control PSC fill factor	0.65	0.65	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM control PSC Jsc	22.7 mA/cm2	22.7 mA/cm2	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM control PSC PCE	14.1%	14.1 %	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM control PSC Voc	0.95 V	0.95 V	—	Table Exact Reported	4 · 3. Results and discussion · Table 1

Photocurrent density-voltage (J-V)

Photoresponse and photoelectrochemistry

PSC with HTM/In10-2 · Electrode

J-V measured under calibrated 450 W xenon lamp; cell area 0.06 cm2 determined by metal aperture.

Geometry: 0.06 cm2 perovskite solar cell
Context: PSC with HTM/In10-2.
Measurement source: 4 · 3. Results and discussion · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HTM/In10-2 PSC fill factor	0.68	0.68	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM/In10-2 PSC Jsc	23.9 mA/cm2	23.9 mA/cm2	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM/In10-2 PSC PCE	15.8%	15.8 %	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM/In10-2 PSC Voc	0.97 V	0.97 V	—	Table Exact Reported	4 · 3. Results and discussion · Table 1

Photocurrent density-voltage (J-V)

Photoresponse and photoelectrochemistry

PSC with HTM/In10-4 · Electrode

J-V measured under calibrated 450 W xenon lamp; cell area 0.06 cm2 determined by metal aperture.

Geometry: 0.06 cm2 perovskite solar cell
Context: PSC with best HTM/In10-4 composition.
Measurement source: 4 · 3. Results and discussion · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PCE enhancement for best HTM/In10-4 versus HTMMarked as a best value within this paper	over 20% enhancement in PCE; from 14.1% to 17.0%	20.6 %	—	Calculated From Reported Rounded Reported	5 · 4. Conclusions · Table 1
HTM/In10-4 PSC fill factorMarked as a best value within this paper	0.70	0.7	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM/In10-4 PSC JscMarked as a best value within this paper	24.3 mA/cm2	24.3 mA/cm2	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM/In10-4 PSC PCEMarked as a best value within this paper	17.0%	17 %	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM/In10-4 PSC VocMarked as a best value within this paper	1.00 V	1 V	—	Table Exact Reported	4 · 3. Results and discussion · Table 1

Photocurrent density-voltage (J-V)

Photoresponse and photoelectrochemistry

PSC with HTM/In10-6 · Electrode

J-V measured under calibrated 450 W xenon lamp; cell area 0.06 cm2 determined by metal aperture.

Geometry: 0.06 cm2 perovskite solar cell
Context: PSC with HTM/In10-6.
Measurement source: 4 · 3. Results and discussion · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HTM/In10-6 PSC fill factor	0.69	0.69	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM/In10-6 PSC Jsc	23.8 mA/cm2	23.8 mA/cm2	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM/In10-6 PSC PCE	16.4%	16.4 %	—	Table Exact Reported	4 · 3. Results and discussion · Table 1
HTM/In10-6 PSC Voc	0.99 V	0.99 V	—	Table Exact Reported	4 · 3. Results and discussion · Table 1

Cyclic voltammetry of HTM and HTM/In10, SI Figure S5 caption only

Voltammetry

HTM/In10-4 film · Thin Film

The SI text and rendered page contain the Figure S5 caption for CV curves of HTM and HTM/In10, but the plot body is not visible in the local rendered/text layer.

Geometry: film/solution CV geometry not extractable from SI figure body
Context: HTM control and HTM/In10 comparison.
Measurement source: S-5 · Supporting Information · Figure S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
SI Figure S5 extraction status	Figure S5 caption is present but the CV plot body is absent/not visible in the local rendered and text layers	—	—	Qualitative Uncertain	S-5 · Supporting Information · Figure S5

Numerical EIS resistance table

Impedance spectroscopy

PSC with HTM/In10-4 · Electrode

Rendered SI Table S2 reports Rsh and Rs values for HTM, HTM/In10-2, HTM/In10-4 and HTM/In10-6 based PSCs.

Geometry: PSC series; assigned to best HTM/In10-4 sample
Context: HTM control and HTM/In10 PSCs.
Measurement source: S-5 to S-6 · Supporting Information · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source