Porosity — Pd uptake and H2S sensing by an amphoteric metal-organic framework with a soft core and rigid side arms

Measurement evidence

Porosity

Pd uptake and H2S sensing by an amphoteric metal-organic framework with a soft core and rigid side arms · Cui J., Wong Y.-L., Zeller M. et al. · Angewandte Chemie - International Edition · 2014 · 14438-14442

1 measurement group · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Gas sorption; CO2 adsorption/desorption and N2 sorption

Gas sorption and porosity

BFMOF-1a desolvated/solvent-exchanged crystals · Single Crystal

Outgassed at 0.03 torr with 2 C/min ramp to 110 C and held 12 h; CO2 isotherms at 273 K; N2 sorption at 77 K.

Temperature: 273 for CO2; 77 for N2
Atmosphere: High purity gases
Context: desolvated pristine host
Measurement source: SI p.S2 and S11 · General Procedure; Figure S4 · Figure S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area from CO2 sorptionMarked as a best value within this paper	318 m2 g-1	—	—	Text Exact Reported	main p.3, article p.14440 · Gas sorption · Figure S4
N2 sorption at 77 K	no significant N2 sorption at 77 K	—	—	Text Qualitative	main p.3, article p.14440 · Gas sorption
Pore volume from CO2 sorptionMarked as a best value within this paper	0.107 cc g-1	—	—	Text Exact Reported	main p.3, article p.14440 · Gas sorption · Figure S4