Spectroscopy — Synergistic Enhancement of Supercapacitors with Cobalt–Copper Bimetal–Organic Framework

5 measurement groups · 22 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CoCu-MOF powder, Co:Cu = 6:1 feed · Powder

Energy-dispersive X-ray spectroscopy of CoCu-MOF material

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EDS Co at%	6.16 at%	—	—	Visual Estimate Exact Reported	2 · Supporting Information · Figure S1
STEM-EDS Co:Cu atom ratio	6.16	—	—	Text Exact Reported	3 · Results and Discussion · Figure S1
EDS Co wt%	21.99 wt%	—	—	Visual Estimate Exact Reported	2 · Supporting Information · Figure S1
EDS Cu at%	1.00 at%	—	—	Visual Estimate Exact Reported	2 · Supporting Information · Figure S1
EDS Cu wt%	3.84 wt%	—	—	Visual Estimate Exact Reported	2 · Supporting Information · Figure S1

CoCu-MOF powder, Co:Cu = 6:1 feed · Powder

FTIR spectra over 4000-400 cm-1 collected with Bruker Tensor 27 at room temperature using KBr dilution; spectra compare Cu-MOF, Co-MOF and CoCu-MOF

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
asymmetric COO- vibration	1574 cm-1	—	—	Text Exact Reported	3 · Results and Discussion · Figure 3
C=O stretching band	1690-1667 cm-1	—	—	Text Range	3 · Results and Discussion · Figure 3
Co-O-H or Cu-O-H stretching band	747-733 cm-1	—	—	Text Range	3 · Results and Discussion · Figure 3
symmetric COO- vibration	1384 cm-1	—	—	Text Exact Reported	3 · Results and Discussion · Figure 3

Co-MOF powder · Powder

Thermo Scientific K-Alpha, Al K-alpha hnu = 1486.6 eV; binding energies referenced to C 1s 284.6 eV

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co2+ Co 2p1/2 binding energy	796.2 eV	—	—	Text Exact Reported	3 · Results and Discussion · Figure 4c
Co2+ Co 2p3/2 binding energy	780.5 eV	—	—	Text Exact Reported	3 · Results and Discussion · Figure 4c
Co3+ Co 2p1/2 binding energy	797.4 eV	—	—	Text Exact Reported	3 · Results and Discussion · Figure 4c
Co3+ Co 2p3/2 binding energy	781.7 eV	—	—	Text Exact Reported	3 · Results and Discussion · Figure 4c

CoCu-MOF powder, Co:Cu = 6:1 feed · Powder

Thermo Scientific K-Alpha, Al K-alpha hnu = 1486.6 eV; binding energies referenced to C 1s 284.6 eV

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CoCu-MOF Cu2+ fraction	17%	0.17 fraction	—	Text Exact Reported	4 · Results and Discussion · Table S1
CoCu-MOF Cu+ fractionMarked as a best value within this paper	83%	0.83 fraction	—	Text Exact Reported	1 · Abstract
Co3+/Co2+ ratio in Co-MOF and CoCu-MOF	about 2.5	—	about	Text Approximate	3 · Results and Discussion · Figure 4c

Cu-MOF powder · Powder

Thermo Scientific K-Alpha, Al K-alpha hnu = 1486.6 eV; binding energies referenced to C 1s 284.6 eV

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-MOF Cu2+ fraction	82%	0.82 fraction	—	Text Exact Reported	4 · Results and Discussion · Table S1
Cu-MOF Cu+ fraction	18%	0.18 fraction	—	Text Exact Reported	4 · Results and Discussion · Table S1
Cu2+ Cu 2p1/2 binding energy	954.4 eV	—	—	Text Exact Reported	4 · Results and Discussion · Figure 4d
Cu2+ Cu 2p3/2 binding energy	934.4 eV	—	—	Text Exact Reported	4 · Results and Discussion · Figure 4d
Cu+ Cu 2p1/2 binding energy	952.6 eV	—	—	Text Exact Reported	4 · Results and Discussion · Figure 4d
Cu+ Cu 2p3/2 binding energy	932.8 eV	—	—	Text Exact Reported	4 · Results and Discussion · Figure 4d