Synthesis · Ag doped Co/Ni bimetallic organic framework for determination of luteolin

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Electrochemical

3 · 2.5 Fabrication of the working electrode · Scheme 1

Metal precursorsAg-CoNi-MOF nanosheets

Solvents2 mL DMF

Additives0.169 g NaNO3

Atmospherenot reported

Temperaturenot reported

Substrate orientationglassy carbon electrode, diameter 3 mm

Scalability contextElectrode fabrication uses 2 mg active material in 2 mL suspension.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Ag-CoNi-MOF nanosheets	2 mg	3 · 2.5 Fabrication of the working electrode · Scheme 1
Solvent	DMF	2 mL	3 · 2.5 Fabrication of the working electrode · Scheme 1
Electrolyte	NaNO3	0.169 g	3 · 2.5 Fabrication of the working electrode · Scheme 1

Complete recipeSource: Main

Route 2: Other

3 · 2.4 Preparation of Ag-CoNi-MOF

Metal precursorsCoNi-MOF; preformed Ag NP solution

Linker precursors2-MeIM already present in CoNi-MOF

Solvents100 mL preformed aqueous Ag NPs solution

Additivesresidual citrate/glucose from Ag NP preparation

Atmospherenot reported

Temperaturenot reported during 120 min sonication

Time2

Work-upcentrifuged, washed three times with deionized water

Activationdried under vacuum at 70 C for 12 h

Scalability context50 mg CoNi-MOF batch loading in 100 mL Ag NP solution.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	CoNi-MOF	50 mg	3 · 2.4 Preparation of Ag-CoNi-MOF
Other	Ag NPs solution	100 mL	3 · 2.4 Preparation of Ag-CoNi-MOF

Complete recipeSource: Main

Route 3: Other

3 · 2.4 Preparation of Ag-CoNi-MOF

Metal precursors0.043 mmol AgNO3

Solventsdeionized water: 100 mL citrate solution; 50 mL AgNO3 solution; 50 mL glucose solution

Additives0.1 mmol trisodium citrate dehydrate

Atmospherenot reported

Temperature94

Time0.5 after glucose addition; 10 min sonication before glucose

Oxidant / reductant2.78 mmol glucose water solution

Work-upnone reported for isolated Ag NPs solution

Scalability contextAqueous batch colloid preparation.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	AgNO3	0.043 mmol	3 · 2.4 Preparation of Ag-CoNi-MOF
Additive	trisodium citrate dehydrate	0.1 mmol	3 · 2.4 Preparation of Ag-CoNi-MOF
Reductant	glucose water solution	2.78 mmol in 50 mL	3 · 2.4 Preparation of Ag-CoNi-MOF
Solvent	deionized water	200 mL total stated	3 · 2.4 Preparation of Ag-CoNi-MOF

Vague recipeSource: Main

Route 4: Electrochemical

3 · 2.5 Fabrication of the working electrode

Metal precursorsCoNi-MOF nanosheets

SolventsDMF, by similar method to Ag-CoNi-MOF/GCE

AdditivesNaNO3, by similar method to Ag-CoNi-MOF/GCE

Atmospherenot reported

Temperaturenot reported

Substrate orientationglassy carbon electrode

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	CoNi-MOF nanosheets	not separately reported	3 · 2.5 Fabrication of the working electrode

Complete recipeSource: Main

Route 5: Other

2 · 2.3 Preparation of CoNi-MOFs

Metal precursors12 mmol Co(NO3)2.6H2O; 4 mmol Ni(NO3)2.6H2O

Linker precursors4 mmol 2-methylimidazole (2-MeIM)

Solventsmethanol: 120 mL for metal salts; 40 mL for 2-MeIM

Atmospherenot reported

TemperatureRT

Time6

Work-upwashed thoroughly with methanol

Activationdried under vacuum at 60 C

Scalability contextBatch solution precipitation/stirring recipe with millimole precursor amounts.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Co(NO3)2.6H2O	12 mmol	2 · 2.3 Preparation of CoNi-MOFs
Metal Source	Ni(NO3)2.6H2O	4 mmol	2 · 2.3 Preparation of CoNi-MOFs
Linker	2-methylimidazole (2-MeIM)	4 mmol	2 · 2.3 Preparation of CoNi-MOFs
Solvent	methanol	120 mL + 40 mL	2 · 2.3 Preparation of CoNi-MOFs