Synthesis · Tuning the Electrical Conductivity of Bimetallic Co–Mn-Based MOFs via Precisely Regulating the Atomic Content of Metal Centers and Study on Their Dye Adsorption Properties

18 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Metal precursorsAs-synthesised MOF1

Linker precursorsFormate framework inherited from as-synthesised sample.

AtmosphereNot specified.

Temperature160

Time24

Oxidant / reductantThermal removal of dimethylammonium guests; Co2+ to Co3+ oxidation proposed after removal.

Work-upNo post-heating workup specified.

ActivationGuest removal by heating at 160 deg C for 24 h.

Scalability contextNo scale or atmosphere details reported for guest-removal step.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	as-synthesised MOF1	not specified	main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Partial recipeSource: Main

Route 2: Other

main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Metal precursorsAs-synthesised MOF2

Linker precursorsFormate framework inherited from as-synthesised sample.

AtmosphereNot specified.

Temperature160

Time24

Oxidant / reductantThermal removal of dimethylammonium guests; Co2+ to Co3+ oxidation proposed after removal.

Work-upNo post-heating workup specified.

ActivationGuest removal by heating at 160 deg C for 24 h.

Scalability contextNo scale or atmosphere details reported for guest-removal step.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	as-synthesised MOF2	not specified	main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Partial recipeSource: Main

Route 3: Other

main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Metal precursorsAs-synthesised MOF3

Linker precursorsFormate framework inherited from as-synthesised sample.

AtmosphereNot specified.

Temperature160

Time24

Oxidant / reductantThermal removal of dimethylammonium guests; Co2+ to Co3+ oxidation proposed after removal.

Work-upNo post-heating workup specified.

ActivationGuest removal by heating at 160 deg C for 24 h.

Scalability contextNo scale or atmosphere details reported for guest-removal step.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	as-synthesised MOF3	not specified	main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Partial recipeSource: Main

Route 4: Other

main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Metal precursorsAs-synthesised MOF4

Linker precursorsFormate framework inherited from as-synthesised sample.

AtmosphereNot specified.

Temperature160

Time24

Oxidant / reductantThermal removal of dimethylammonium guests; Co2+ to Co3+ oxidation proposed after removal.

Work-upNo post-heating workup specified.

ActivationGuest removal by heating at 160 deg C for 24 h.

Scalability contextNo scale or atmosphere details reported for guest-removal step.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	as-synthesised MOF4	not specified	main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Partial recipeSource: Main

Route 5: Other

main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Metal precursorsAs-synthesised MOF5

Linker precursorsFormate framework inherited from as-synthesised sample.

AtmosphereNot specified.

Temperature160

Time24

Oxidant / reductantThermal removal of dimethylammonium guests; Co2+ to Co3+ oxidation proposed after removal.

Work-upNo post-heating workup specified.

ActivationGuest removal by heating at 160 deg C for 24 h.

Scalability contextNo scale or atmosphere details reported for guest-removal step.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	as-synthesised MOF5	not specified	main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Partial recipeSource: Main

Route 6: Other

main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Metal precursorsAs-synthesised MOF6

Linker precursorsFormate framework inherited from as-synthesised sample.

AtmosphereNot specified.

Temperature160

Time24

Oxidant / reductantThermal removal of dimethylammonium guests; Co2+ to Co3+ oxidation proposed after removal.

Work-upNo post-heating workup specified.

ActivationGuest removal by heating at 160 deg C for 24 h.

Scalability contextNo scale or atmosphere details reported for guest-removal step.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	as-synthesised MOF6	not specified	main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Partial recipeSource: Main

Route 7: Other

main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Metal precursorsAs-synthesised MOF7

Linker precursorsFormate framework inherited from as-synthesised sample.

AtmosphereNot specified.

Temperature160

Time24

Oxidant / reductantThermal removal of dimethylammonium guests; Co2+ to Co3+ oxidation proposed after removal.

Work-upNo post-heating workup specified.

ActivationGuest removal by heating at 160 deg C for 24 h.

Scalability contextNo scale or atmosphere details reported for guest-removal step.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	as-synthesised MOF7	not specified	main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Partial recipeSource: Main

Route 8: Other

main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Metal precursorsAs-synthesised MOF8

Linker precursorsFormate framework inherited from as-synthesised sample.

AtmosphereNot specified.

Temperature160

Time24

Oxidant / reductantThermal removal of dimethylammonium guests; Co2+ to Co3+ oxidation proposed after removal.

Work-upNo post-heating workup specified.

ActivationGuest removal by heating at 160 deg C for 24 h.

Scalability contextNo scale or atmosphere details reported for guest-removal step.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	as-synthesised MOF8	not specified	main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Partial recipeSource: Main

Route 9: Other

main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Metal precursorsAs-synthesised MOF9

Linker precursorsFormate framework inherited from as-synthesised sample.

AtmosphereNot specified.

Temperature160

Time24

Oxidant / reductantThermal removal of dimethylammonium guests; Co2+ to Co3+ oxidation proposed after removal.

Work-upNo post-heating workup specified.

ActivationGuest removal by heating at 160 deg C for 24 h.

Scalability contextNo scale or atmosphere details reported for guest-removal step.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	as-synthesised MOF9	not specified	main p.6, article p.15753 · Results and discussion · Figure 9/Table 3

Partial recipeSource: Main

Route 10: Solvothermal

main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Metal precursors1 mmol (0.197 g) manganese chloride; 3 mmol (0.711 g) cobalt chloride

Linker precursorsNo added organic linker; formate generated in situ from DMF decomposition.

Solvents15 mL N,N-dimethylformamide (DMF)

Additives2 mL dilute hydrochloric acid

AtmosphereAutogenous pressure in a 50 mL Teflon-lined stainless-steel autoclave; gas atmosphere not otherwise specified.

Temperature120

Time48

Work-upCooled to room temperature at 10 deg C/h; crystals collected and dried at room temperature overnight. Reported yield 70-75%.

ActivationNone reported for as-synthesised material.

Scalability contextSimple solvothermal batch in a 50 mL autoclave; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	manganese chloride	1 mmol (0.197 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Metal Source	cobalt chloride	3 mmol (0.711 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Solvent	N,N-dimethylformamide (DMF)	15 mL	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Acid	dilute hydrochloric acid	2 mL · dilute	main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Partial recipeSource: Main

Route 11: Solvothermal

main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Metal precursors2 mmol (0.394 g) manganese chloride; 2 mmol (0.474 g) cobalt chloride

Linker precursorsNo added organic linker; formate generated in situ from DMF decomposition.

Solvents15 mL N,N-dimethylformamide (DMF)

Additives2 mL dilute hydrochloric acid

AtmosphereAutogenous pressure in a 50 mL Teflon-lined stainless-steel autoclave; gas atmosphere not otherwise specified.

Temperature120

Time48

Work-upCooled to room temperature at 10 deg C/h; crystals collected and dried at room temperature overnight. Reported yield 70-75%.

ActivationNone reported for as-synthesised material.

Scalability contextSimple solvothermal batch in a 50 mL autoclave; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	manganese chloride	2 mmol (0.394 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Metal Source	cobalt chloride	2 mmol (0.474 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Solvent	N,N-dimethylformamide (DMF)	15 mL	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Acid	dilute hydrochloric acid	2 mL · dilute	main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Partial recipeSource: Main

Route 12: Solvothermal

main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Metal precursors3 mmol (0.591 g) manganese chloride; 1 mmol (0.237 g) cobalt chloride

Linker precursorsNo added organic linker; formate generated in situ from DMF decomposition.

Solvents15 mL N,N-dimethylformamide (DMF)

Additives2 mL dilute hydrochloric acid

AtmosphereAutogenous pressure in a 50 mL Teflon-lined stainless-steel autoclave; gas atmosphere not otherwise specified.

Temperature120

Time48

Work-upCooled to room temperature at 10 deg C/h; crystals collected and dried at room temperature overnight. Reported yield 70-75%.

ActivationNone reported for as-synthesised material.

Scalability contextSimple solvothermal batch in a 50 mL autoclave; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	manganese chloride	3 mmol (0.591 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Metal Source	cobalt chloride	1 mmol (0.237 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Solvent	N,N-dimethylformamide (DMF)	15 mL	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Acid	dilute hydrochloric acid	2 mL · dilute	main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Partial recipeSource: Main

Route 13: Solvothermal

main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Metal precursors3.42 mmol (0.673 g) manganese chloride; 0.57 mmol (0.135 g) cobalt chloride

Linker precursorsNo added organic linker; formate generated in situ from DMF decomposition.

Solvents15 mL N,N-dimethylformamide (DMF)

Additives2 mL dilute hydrochloric acid

AtmosphereAutogenous pressure in a 50 mL Teflon-lined stainless-steel autoclave; gas atmosphere not otherwise specified.

Temperature120

Time48

Work-upCooled to room temperature at 10 deg C/h; crystals collected and dried at room temperature overnight. Reported yield 70-75%.

ActivationNone reported for as-synthesised material.

Scalability contextSimple solvothermal batch in a 50 mL autoclave; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	manganese chloride	3.42 mmol (0.673 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Metal Source	cobalt chloride	0.57 mmol (0.135 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Solvent	N,N-dimethylformamide (DMF)	15 mL	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Acid	dilute hydrochloric acid	2 mL · dilute	main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Partial recipeSource: Main

Route 14: Solvothermal

main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Metal precursors0.67 mmol (0.131 g) manganese chloride; 3.35 mmol (0.79 g) cobalt chloride

Linker precursorsNo added organic linker; formate generated in situ from DMF decomposition.

Solvents15 mL N,N-dimethylformamide (DMF)

Additives2 mL dilute hydrochloric acid

AtmosphereAutogenous pressure in a 50 mL Teflon-lined stainless-steel autoclave; gas atmosphere not otherwise specified.

Temperature120

Time48

Work-upCooled to room temperature at 10 deg C/h; crystals collected and dried at room temperature overnight. Reported yield 75-80%.

ActivationNone reported for as-synthesised material.

Scalability contextSimple solvothermal batch in a 50 mL autoclave; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	manganese chloride	0.67 mmol (0.131 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Metal Source	cobalt chloride	3.35 mmol (0.79 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Solvent	N,N-dimethylformamide (DMF)	15 mL	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Acid	dilute hydrochloric acid	2 mL · dilute	main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Partial recipeSource: Main

Route 15: Solvothermal

main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Metal precursors0.57 mmol (0.112 g) manganese chloride; 3.42 mmol (0.81 g) cobalt chloride

Linker precursorsNo added organic linker; formate generated in situ from DMF decomposition.

Solvents15 mL N,N-dimethylformamide (DMF)

Additives2 mL dilute hydrochloric acid

AtmosphereAutogenous pressure in a 50 mL Teflon-lined stainless-steel autoclave; gas atmosphere not otherwise specified.

Temperature120

Time48

Work-upCooled to room temperature at 10 deg C/h; crystals collected and dried at room temperature overnight. Reported yield 75-80%.

ActivationNone reported for as-synthesised material.

Scalability contextSimple solvothermal batch in a 50 mL autoclave; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	manganese chloride	0.57 mmol (0.112 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Metal Source	cobalt chloride	3.42 mmol (0.81 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Solvent	N,N-dimethylformamide (DMF)	15 mL	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Acid	dilute hydrochloric acid	2 mL · dilute	main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Partial recipeSource: Main

Route 16: Solvothermal

main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Metal precursors0.5 mmol (0.098 g) manganese chloride; 3.5 mmol (0.82 g) cobalt chloride

Linker precursorsNo added organic linker; formate generated in situ from DMF decomposition.

Solvents15 mL N,N-dimethylformamide (DMF)

Additives2 mL dilute hydrochloric acid

AtmosphereAutogenous pressure in a 50 mL Teflon-lined stainless-steel autoclave; gas atmosphere not otherwise specified.

Temperature120

Time48

Work-upCooled to room temperature at 10 deg C/h; crystals collected and dried at room temperature overnight. Reported yield 75-80%.

ActivationNone reported for as-synthesised material.

Scalability contextSimple solvothermal batch in a 50 mL autoclave; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	manganese chloride	0.5 mmol (0.098 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Metal Source	cobalt chloride	3.5 mmol (0.82 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Solvent	N,N-dimethylformamide (DMF)	15 mL	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Acid	dilute hydrochloric acid	2 mL · dilute	main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Partial recipeSource: Main

Route 17: Solvothermal

main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Metal precursors0.4 mmol (0.07 g) manganese chloride; 3.6 mmol (0.85 g) cobalt chloride

Linker precursorsNo added organic linker; formate generated in situ from DMF decomposition.

Solvents15 mL N,N-dimethylformamide (DMF)

Additives2 mL dilute hydrochloric acid

AtmosphereAutogenous pressure in a 50 mL Teflon-lined stainless-steel autoclave; gas atmosphere not otherwise specified.

Temperature120

Time48

Work-upCooled to room temperature at 10 deg C/h; crystals collected and dried at room temperature overnight. Reported yield 75-80%.

ActivationNone reported for as-synthesised material.

Scalability contextSimple solvothermal batch in a 50 mL autoclave; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	manganese chloride	0.4 mmol (0.07 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Metal Source	cobalt chloride	3.6 mmol (0.85 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Solvent	N,N-dimethylformamide (DMF)	15 mL	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Acid	dilute hydrochloric acid	2 mL · dilute	main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Partial recipeSource: Main

Route 18: Solvothermal

main p.2, article p.15749 · 2.2. Synthesis of the MOFs

Metal precursors0.36 mmol (0.07 g) manganese chloride; 3.63 mmol (0.86 g) cobalt chloride

Linker precursorsNo added organic linker; formate generated in situ from DMF decomposition.

Solvents15 mL N,N-dimethylformamide (DMF)

Additives2 mL dilute hydrochloric acid

AtmosphereAutogenous pressure in a 50 mL Teflon-lined stainless-steel autoclave; gas atmosphere not otherwise specified.

Temperature120

Time48

Work-upCooled to room temperature at 10 deg C/h; crystals collected and dried at room temperature overnight. Reported yield 75-80%.

ActivationNone reported for as-synthesised material.

Scalability contextSimple solvothermal batch in a 50 mL autoclave; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	manganese chloride	0.36 mmol (0.07 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Metal Source	cobalt chloride	3.63 mmol (0.86 g)	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Solvent	N,N-dimethylformamide (DMF)	15 mL	main p.2, article p.15749 · 2.2. Synthesis of the MOFs
Acid	dilute hydrochloric acid	2 mL · dilute	main p.2, article p.15749 · 2.2. Synthesis of the MOFs