Electrical Transport — Redox-Active Metal-Organic Frameworks with Three-Dimensional Lattice Containing the m-Tetrathiafulvalene-Tetrabenzoate

3 measurement groups · 19 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

two-probe electrical conductivity

Electrical conductivity

Er-m-TTFTB red rod-like/needle-like single crystal · Single Crystal

Same two-probe single-crystal method; SI Table S2 dimensions length 0.034 cm, width 0.004 cm, thickness 0.004 cm.

Temperature: room temperature
Atmosphere: ambient
Geometry: two-contact probe with conductive carbon adhesive
Context: pristine framework single crystal
Measurement source: 6,9 · 2.3; 3.10 · Figures S10; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
cross-sectional area	1.6e-05 cm2	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
single-crystal channel length	0.034 cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
single-crystal thickness	0.004 cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
single-crystal width	0.004 cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
electrical conductance	4.5e-10 S	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
room-temperature single-crystal electrical conductivityMarked as a best value within this paper	9.6e-07 S/cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2

two-probe electrical conductivity

Electrical conductivity

Gd-m-TTFTB red rod-like/needle-like single crystal · Single Crystal

Same two-probe single-crystal method; SI Table S2 dimensions length 0.007 cm, width 0.005 cm, thickness 0.005 cm.

Temperature: room temperature
Atmosphere: ambient
Geometry: two-contact probe with conductive carbon adhesive
Context: pristine framework single crystal
Measurement source: 6,9 · 2.3; 3.10 · Figures S11; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
cross-sectional area	2.5e-05 cm2	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
single-crystal channel length	0.007 cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
single-crystal thickness	0.005 cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
single-crystal width	0.005 cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
electrical conductance	3.7e-10 S	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
room-temperature single-crystal electrical conductivityMarked as a best value within this paper	1.0e-07 S/cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2

two-probe electrical conductivity

Electrical conductivity

Tb-m-TTFTB red rod-like/needle-like single crystal · Single Crystal

Needle-like single crystal; Keithley 2400 source meter on CRX-4K closed-cycle refrigerator probe station at room temperature; conductive carbon adhesive contacts; voltage swept from -1.5 to 1.5 V under ambient conditions.

Temperature: room temperature
Atmosphere: ambient
Geometry: two-contact probe, long horizontal/vertical single-crystal direction; SI Table S2 dimensions length 0.028 cm, width 0.006 cm, thickness 0.006 cm
Context: pristine framework single crystal
Measurement source: 6,9 · 2.3 Absorption Spectra and Semiconducting Properties; 3.10 Electrical Conductivity · Figures S8-S9; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
reported Ln-TTFTB comparator conductivity	10^-8 S cm^-1 in powder state	—	—	Text Approximate	6 · 2.3 Absorption Spectra and Semiconducting Properties
cross-sectional area	3.6e-05 cm2	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
single-crystal channel length	0.028 cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
single-crystal thickness	0.006 cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
single-crystal width	0.006 cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
electrical conductance	7.0e-10 S	—	—	SI Table Exact Reported	3 · Table S2 · Table S2
room-temperature single-crystal electrical conductivityMarked as a best value within this paper	5.4e-07 S/cm	—	—	SI Table Exact Reported	3 · Table S2 · Table S2