Electrochemistry Application — Redox-Active Metal-Organic Frameworks with Three-Dimensional Lattice Containing the m-Tetrathiafulvalene-Tetrabenzoate

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

solid-state DC cyclic voltammetry

Voltammetry

Er-m-TTFTB polycrystalline/powder sample · Powder

Same solid-state CV setup as Tb; SI Figure S6 reports Er-m-TTFTB consecutive cycles and scan-rate dependence.

Atmosphere: ambient electrolyte
Geometry: powder paste on glassy carbon electrode
Context: pristine framework
Measurement source: 7 · Figure S6 caption · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first reversible one-electron redox process	around 0.21 V vs Fc/Fc+	—	—	Text Approximate	4-5 · 2.2 Cyclic Voltammetry · Figure 3; Figures S6-S7
second reversible one-electron redox process	around 0.48 V vs Fc/Fc+	—	—	Text Approximate	4-5 · 2.2 Cyclic Voltammetry · Figure 3; Figures S6-S7

solid-state DC cyclic voltammetry

Voltammetry

Gd-m-TTFTB polycrystalline/powder sample · Powder

Same solid-state CV setup as Tb; SI Figure S7 reports Gd-m-TTFTB consecutive cycles and scan-rate dependence.

Atmosphere: ambient electrolyte
Geometry: powder paste on glassy carbon electrode
Context: pristine framework
Measurement source: 8 · Figure S7 caption · Figure S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first reversible one-electron redox process	around 0.21 V vs Fc/Fc+	—	—	Text Approximate	4-5 · 2.2 Cyclic Voltammetry · Figure 3; Figures S6-S7
second reversible one-electron redox process	around 0.48 V vs Fc/Fc+	—	—	Text Approximate	4-5 · 2.2 Cyclic Voltammetry · Figure 3; Figures S6-S7

solid-state DC cyclic voltammetry

Voltammetry

Tb-m-TTFTB polycrystalline/powder sample · Powder

0.1 M LiBF4 in distilled CH3CN; glassy carbon working electrode with powder sample paste in ethanol; Pt wire auxiliary; Ag wire quasi-reference; ferrocene internal standard; potentials vs Fc/Fc+.

Atmosphere: ambient electrolyte
Geometry: powder paste on 3.0 mm glassy carbon electrode
Context: pristine framework
Measurement source: 4-5,9 · 2.2 Cyclic Voltammetry; 3.8 Solid CV · Figure 3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CV reversibility over repeated scans	current associated with the two redox processes was almost the same over multiple scans	—	—	Text Qualitative	5 · 2.2 Cyclic Voltammetry · Figure 3
first reversible one-electron redox process	around 0.21 V vs Fc/Fc+	—	—	Text Approximate	4-5 · 2.2 Cyclic Voltammetry · Figure 3; Figures S6-S7
second reversible one-electron redox process	around 0.48 V vs Fc/Fc+	—	—	Text Approximate	4-5 · 2.2 Cyclic Voltammetry · Figure 3; Figures S6-S7