Electrochemistry Application — Nanopore-induced host-guest charge transfer phenomena in a metal-organic framework

Measurement evidence

Electrochemistry Application

Nanopore-induced host-guest charge transfer phenomena in a metal-organic framework · Yamamoto S., Pirillo J., Hijikata Y. et al. · Chemical Science · 2018 · 3282-3289

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Solid-state cyclic voltammetry

Voltammetry

As-prepared Mn-MOF crystals · Single Crystal

Mn-MOF and 2,7-AQDC measured under conditions from prior paper; potentials versus Li+/Li.

Geometry: solid-state electrochemical configuration
Context: pristine framework control
Measurement source: SI p.4 · S3. Cyclic voltammetry · Fig. S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Solid-state anthraquinone E1/2 range in Mn-MOF and AQDC	around 2.4-2.5 V vs Li+/Li	—	—	Caption Range	SI p.4 · S3. Cyclic voltammetry · Fig. S3

Cyclic voltammetry

Voltammetry

Free 2,7-AQDC, TTF and TMPDA in DMF electrolyte · Unknown

Saturated DMF solution with 1.0 mol/L [Bu4N]PF6 electrolyte; potentials versus Ag/AgCl.

Geometry: solution electrochemical cell
Context: free donor/acceptor model molecules
Measurement source: SI p.4 · S3. Cyclic voltammetry · Fig. S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
2,7-AQDC first reduction potential	-0.67 V vs Ag/AgCl	—	—	Caption Exact Reported	SI p.4 · S3. Cyclic voltammetry · Fig. S2
TMPDA first oxidation potential	0.37 V vs Ag/AgCl	—	—	Caption Exact Reported	SI p.4 · S3. Cyclic voltammetry · Fig. S2
TTF first oxidation potential	0.45 V vs Ag/AgCl	—	—	Caption Exact Reported	SI p.4 · S3. Cyclic voltammetry · Fig. S2