Other — Nanopore-induced host-guest charge transfer phenomena in a metal-organic framework

3 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Compound 1 Mn-MOF 5TTF crystals · Single Crystal

DC magnetisation at 1000 Oe from 2-300 K; Curie-Weiss fitting from 50-300 K.

Temperature: 2-300
Context: guest-loaded target sample
Measurement source: p.6 · Experimental evidence of charge transfer · Fig. S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Compound 1 Curie constant	24.95 cm3 mol-1 K	—	—	Caption Exact Reported	SI p.10 · S8. Magnetic properties · Fig. S9
Estimated charge of TTF guest ensemble in compound 1	(TTF5)0.15+ Mn-MOF0.15-	—	qualitative estimate; AF interactions ignored	Calculated From Reported Qualitative	p.6 · Experimental evidence of charge transfer

Compound 2 Mn-MOF 7TMPDA crystals · Single Crystal

DC magnetisation at 1000 Oe from 2-300 K; Curie-Weiss fitting from 50-300 K.

Temperature: 2-300
Context: guest-loaded target sample
Measurement source: p.6 · Experimental evidence of charge transfer · Fig. S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Compound 2 Curie constant	30.46 cm3 mol-1 K	—	—	Caption Exact Reported	SI p.10 · S8. Magnetic properties · Fig. S9
Estimated charge of TMPDA guest ensemble in compound 2	(TMPDA7)7+ Mn-MOF7-	—	qualitative estimate; AF interactions ignored	Calculated From Reported Qualitative	p.6 · Experimental evidence of charge transfer

As-prepared Mn-MOF crystals · Single Crystal

DC magnetisation at 1000 Oe from 2-300 K; Curie-Weiss fitting from 50-300 K.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Mn-MOF Curie constant	24.84 cm3 mol-1 K	—	—	Caption Exact Reported	SI p.10 · S8. Magnetic properties · Fig. S9
Mn7 SBU giant spin approximation	S=13/2, g=2.04, zJ=-0.177 cm-1; residue=0.11%	—	—	Caption Exact Reported	SI p.11 · S8. Magnetic properties · Fig. S10