Other — Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons

Measurement evidence

Other

Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons · Hariri R., Dehghanpour S. · Applied Organometallic Chemistry · 2021 · e6422

1 measurement group · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Thermogravimetric analysis (TGA)

PCN-222(Fe) · Powder

TGA thermal stability of PCN-222(Fe, Co, Ni, and Cu) using Mettler Toledo TGA/DSC at 10 C/min in air; curves in SI Figure S4.

Atmosphere
air
Context
pristine metalloporphyrinic MOF series
Measurement source
3 · Characterization of catalyst · Figure S4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
First TGA weight-loss stage thresholdfirst weight loss occurs below 160 C due to removal of entrapped guest solventbelowText
Approximate
3 · Characterization of catalyst · Figure S4
Thermal stability with negligible weight loss up to 300 Cnegligible weight loss is observed up to 300 Cup toText
Approximate
3 · Characterization of catalyst · Figure S4
TGA residue for PCN-222(Co)26%Text
Rounded Reported
3 · Characterization of catalyst · Figure S4
TGA residue for PCN-222(Cu)30%Text
Rounded Reported
3 · Characterization of catalyst · Figure S4
TGA residue for PCN-222(Fe)28%Text
Rounded Reported
3 · Characterization of catalyst · Figure S4
TGA residue for PCN-222(Ni)27%Text
Rounded Reported
3 · Characterization of catalyst · Figure S4