cMOF Evidence Base

Synthesis evidence

Conductive Metal−Organic Frameworks for Rechargeable LiOH-Based Li−O2 Batteries

Wu Y., Zhang K., Wang H. et al. · ACS Applied Energy Materials · 2024 · 12027-12035

8 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Hydrothermal

12028 (p002) · 2.2 Synthesis of cMOF Catalysts

Metal precursorsCo(OAc)2.4H2O only
Linker precursorsHHTP
SolventsH2O and DMF
Atmospherenot specified
Temperature85
Time8
Work-upSimilar to NiCo-HHTP: cool, centrifuge, wash with water and ethanol.
ActivationDry in a vacuum oven at 50 C.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(OAc)2.4H2Onot separately stated12028 (p002) · 2.2 Synthesis of cMOF Catalysts
LinkerHHTPnot separately stated12028 (p002) · 2.2 Synthesis of cMOF Catalysts
SolventH2Onot separately stated12028 (p002) · 2.2 Synthesis of cMOF Catalysts
SolventDMFnot separately stated12028 (p002) · 2.2 Synthesis of cMOF Catalysts
Complete recipeSource: Main

Route 2: Other

12028 (p002) · 2.3 Preparation of Electrodes

Solventswater in PTFE dispersion
AdditivesKetjen Black, PTFE
Atmosphereair exposure avoided after drying; transferred into glovebox in airtight container
Temperature60
Time12
Substrate orientationpressed onto carbon paper
Work-upSimilar film rolling and punching procedure.
ActivationDry in vacuo at 60 C for 12 h.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
AdditiveKB90 wt %12028 (p002) · 2.3 Preparation of Electrodes
AdditivePTFE10 wt %12028 (p002) · 2.3 Preparation of Electrodes
Complete recipeSource: Main

Route 3: Other

12028 (p002) · 2.3 Preparation of Electrodes

Solventswater in 60 wt % PTFE dispersion
AdditivesKetjen Black, PTFE
Atmosphereair exposure avoided after drying; transferred into glovebox in airtight container
Temperature60
Time12
Substrate orientationpressed onto carbon paper
Work-upKnead, roll into thin film, punch 12 mm disks, press onto carbon paper.
ActivationDry in vacuo at 60 C for 12 h.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
AdditiveKB60 mass parts12028 (p002) · 2.3 Preparation of Electrodes
Othercatalyst powders30 mass parts12028 (p002) · 2.3 Preparation of Electrodes
AdditivePTFE dispersion in water10 mass parts; 60 wt % dispersion · 60 wt %12028 (p002) · 2.3 Preparation of Electrodes
Vague recipeSource: Both

Route 4: Hydrothermal

S2 (p002) · Figure S1 caption · Figure S1

Metal precursorsNi and Co acetate precursors, feed ratio Ni:Co = 1:2
Linker precursorsHHTP
SolventsH2O and DMF
Atmospherenot specified
Temperature85
Time8
Work-upAssumed same as NiCo-HHTP; not separately stated.
ActivationAssumed same as NiCo-HHTP; not separately stated.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceNi acetate precursorfeed ratio x = 1S2 (p002) · Figure S1 caption · Figure S1
Metal SourceCo acetate precursorfeed ratio y = 2S2 (p002) · Figure S1 caption · Figure S1
LinkerHHTPnot statedS2 (p002) · Figure S1 caption · Figure S1
Vague recipeSource: Both

Route 5: Hydrothermal

S2 (p002) · Figure S1 caption · Figure S1

Metal precursorsNi and Co acetate precursors, feed ratio Ni:Co = 2:1
Linker precursorsHHTP
SolventsH2O and DMF
Atmospherenot specified
Temperature85
Time8
Work-upAssumed same as NiCo-HHTP; not separately stated.
ActivationAssumed same as NiCo-HHTP; not separately stated.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceNi acetate precursorfeed ratio x = 2S2 (p002) · Figure S1 caption · Figure S1
Metal SourceCo acetate precursorfeed ratio y = 1S2 (p002) · Figure S1 caption · Figure S1
LinkerHHTPnot statedS2 (p002) · Figure S1 caption · Figure S1
Partial recipeSource: Main

Route 6: Hydrothermal

12028 (p002) · 2.2 Synthesis of cMOF Catalysts

Metal precursorsNi(OAc)2.4H2O only
Linker precursorsHHTP
SolventsH2O and DMF
Atmospherenot specified
Temperature85
Time8
Work-upSimilar to NiCo-HHTP: cool, centrifuge, wash with water and ethanol.
ActivationDry in a vacuum oven at 50 C.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceNi(OAc)2.4H2Onot separately stated12028 (p002) · 2.2 Synthesis of cMOF Catalysts
LinkerHHTPnot separately stated12028 (p002) · 2.2 Synthesis of cMOF Catalysts
SolventH2Onot separately stated12028 (p002) · 2.2 Synthesis of cMOF Catalysts
SolventDMFnot separately stated12028 (p002) · 2.2 Synthesis of cMOF Catalysts
Complete recipeSource: Main

Route 7: Hydrothermal

12028 (p002) · 2.2 Synthesis of cMOF Catalysts

Metal precursorsCo(OAc)2.4H2O and Ni(OAc)2.4H2O
Linker precursorsHHTP
SolventsH2O and DMF
Atmospherenot specified
Temperature85
Time8
Work-upCool to room temperature; collect precipitate by centrifugation; wash with water and ethanol.
ActivationDry in a vacuum oven at 50 C.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(OAc)2.4H2O0.4 mmol12028 (p002) · 2.2 Synthesis of cMOF Catalysts
Metal SourceNi(OAc)2.4H2O0.4 mmol12028 (p002) · 2.2 Synthesis of cMOF Catalysts
LinkerHHTP0.4 mmol12028 (p002) · 2.2 Synthesis of cMOF Catalysts
SolventH2O10 mL for metal salts12028 (p002) · 2.2 Synthesis of cMOF Catalysts
SolventDMF10 mL for HHTP dispersion12028 (p002) · 2.2 Synthesis of cMOF Catalysts
Partial recipeSource: Main

Route 8: Other

12028 (p002) · 2.4 Cell Assembly and Electrochemical Measurements · Figures S20-S21

Solventsisopropanol
AdditivesLiOH or Li2CO3 preload, PTFE powder
Atmospherecharged in argon atmosphere
Substrate orientationcoated onto nickel mesh
Work-upMix catalyst with LiOH or Li2CO3 at 3:1 mass ratio with PTFE powder in isopropanol to create slurries; coat onto nickel mesh.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherM-HHTP catalyst3 mass parts12028 (p002) · 2.4 Cell Assembly and Electrochemical Measurements · Figures S20-S21
AdditiveLiOH or Li2CO31 mass part; about 2 mg cm-2 loading12028 (p002) · 2.4 Cell Assembly and Electrochemical Measurements · Figures S20-S21
AdditivePTFE powdernot stated12028 (p002) · 2.4 Cell Assembly and Electrochemical Measurements · Figures S20-S21
Solventisopropanolnot stated12028 (p002) · 2.4 Cell Assembly and Electrochemical Measurements · Figures S20-S21