cMOF Evidence Base
Other — Enhanced VOC adsorption capacity on MOF thin layer with reduced particle size by cryogrinding and microwave method

Measurement evidence

Other

Enhanced VOC adsorption capacity on MOF thin layer with reduced particle size by cryogrinding and microwave method · Gaikwad S., Kim Y., Gaikwad R. et al. · Journal of Environmental Chemical Engineering · 2022 · 107567

3 measurement groups · 36 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

QCM quartz weighing before and after MOF coating

All MOF thin layers on QCM crystals · Electrode

Weights of QCM quartz crystals before and after MOF layer fabrication, reported in SI Table S1.

Geometry
MOF layer on QCM quartz crystal
Context
Pristine MOF thin layers on QCM crystals.
Measurement source
10 · Supporting Information · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Calculated MOF coating mass on QCM: HKUST-1 - AC0.4512 - 0.4415 = 0.0097 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
Calculated MOF coating mass on QCM: HKUST-1 - BC0.4510 - 0.4410 = 0.0100 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
Calculated MOF coating mass on QCM: MIL-101 - AC0.4488 - 0.4400 = 0.0088 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
Calculated MOF coating mass on QCM: MIL-101 - BC0.4495 - 0.4399 = 0.0096 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
Calculated MOF coating mass on QCM: UiO-66 - AC0.4506 - 0.4417 = 0.0089 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
Calculated MOF coating mass on QCM: UiO-66 - BC0.4511 - 0.4413 = 0.0098 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
Calculated MOF coating mass on QCM: UTSA-16 - microwave - AC0.4515 - 0.4418 = 0.0097 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
Calculated MOF coating mass on QCM: UTSA-16 - microwave - BC0.4525 - 0.4421 = 0.0104 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
Calculated MOF coating mass on QCM: UTSA-16 - solvothermal0.4520 - 0.4414 = 0.0106 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
Calculated MOF coating mass on QCM: ZIF-80.4475 - 0.4412 = 0.0063 g——Calculated From Reported
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: HKUST-1 - AC0.4512 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: HKUST-1 - BC0.4510 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: MIL-101 - AC0.4488 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: MIL-101 - BC0.4495 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: UiO-66 - AC0.4506 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: UiO-66 - BC0.4511 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: UTSA-16 - microwave - AC0.4515 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: UTSA-16 - microwave - BC0.4525 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: UTSA-16 - solvothermal0.4520 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight after coating: ZIF-80.4475 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: HKUST-1 - AC0.4415 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: HKUST-1 - BC0.4410 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: MIL-101 - AC0.4400 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: MIL-101 - BC0.4399 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: UiO-66 - AC0.4417 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: UiO-66 - BC0.4413 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: UTSA-16 - microwave - AC0.4418 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: UTSA-16 - microwave - BC0.4421 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: UTSA-16 - solvothermal0.4414 g——SI Table
Exact Reported		10 · Supporting Information · Table S1
QCM quartz weight before coating: ZIF-80.4412 g——SI Table
Exact Reported		10 · Supporting Information · Table S1

VOC saturation vapour pressure reference

All MOF powder samples in paper · Powder

Saturation vapour pressures at 25 degC used for volumetric adsorption isotherms.

Temperature
298
Atmosphere
VOC vapour
Context
Reference conditions for all MOF volumetric VOC adsorption measurements.
Measurement source
11 · Supporting Information · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Saturation vapour pressure at 25 degC: Benzene0.128 bar——SI Table
Exact Reported		11 · Supporting Information · Table S3
Saturation vapour pressure at 25 degC: Chlorobenzene0.016 bar——SI Table
Exact Reported		11 · Supporting Information · Table S3
Saturation vapour pressure at 25 degC: Toluene0.038 bar——SI Table
Exact Reported		11 · Supporting Information · Table S3

Thermogravimetric analysis

Thermogravimetric analysis

All MOF powder samples in paper · Powder

Heating to 800 degC at 5 degC/min under N2 flow of 50 mL/min.

Atmosphere
N2
Context
Pristine MOF powders.
Measurement source
6 · 2.2.7 and Results · Fig. 8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
UiO-66 framework decomposition range400-580 degC—rangeText
Range		9 · Results · Fig. 8
TGA initial mass loss for most MOFsabout 10-20% from 80 to 180 degC—rangeText
Range		9 · Results · Fig. 8
ZIF-8 thermal stability limitstable up to 420 degC——Text
Rounded Reported		9 · Results · Fig. 8