Partial recipeSource: Main
Route 1: Liquid Liquid Interface
p002 · Synthesis of compound 1
Metal precursorsCu(NO3)2.3H2O (0.048 g, 0.2 mmol) in H2O (2 mL)
Linker precursors4-phpy (0.031 g, 0.2 mmol) in MeOH (2 mL); H2fum (0.023 g, 0.2 mmol) neutralised with Et3N (0.021 g, 0.2 mmol) in EtOH (2 mL)
SolventsMeOH, H2O, 1:1 MeOH/H2O buffer solution, EtOH
AdditivesEt3N base
Atmospherenot stated
Temperaturenot stated
Time72
Work-upBlock-shaped blue crystals isolated; no washing/drying procedure stated.
Activationnot stated
Scalability contextSmall-batch layered crystal growth; 0.071 g product, 70% yield.
Show 7 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Cu(NO3)2.3H2O | 0.048 g, 0.2 mmol | p002 · Synthesis of compound 1 |
| Linker | 4-phpy | 0.031 g, 0.2 mmol | p002 · Synthesis of compound 1 |
| Linker | H2fum | 0.023 g, 0.2 mmol | p002 · Synthesis of compound 1 |
| Base | Et3N | 0.021 g, 0.2 mmol | p002 · Synthesis of compound 1 |
| Solvent | MeOH | 2 mL for 4-phpy plus 1 mL equivalent in 2 mL 1:1 MeOH/H2O buffer | p002 · Synthesis of compound 1 |
| Solvent | H2O | 2 mL for Cu salt plus 1 mL equivalent in 2 mL 1:1 MeOH/H2O buffer | p002 · Synthesis of compound 1 |
| Solvent | EtOH | 2 mL | p002 · Synthesis of compound 1 |