Complete recipeSource: Main
Route 1: Other
2 · Experimental Section - Synthesis of Compound 1 · Scheme 1
Metal precursors[Fe2(S2C6H2Cl2)(CO)6] (300 mg, 0.61 mmol); K2CO3 (120 mg, 0.86 mmol)
Linker precursorsH2S2C6H2Cl2 (386 mg, 1.83 mmol)
SolventsPreviously degassed DMF (15 mL) for reaction; THF with a few drops of DMF, followed by H2O and n-hexane for crystallisation
AdditivesK2CO3 base; H2O and n-hexane added during crystallisation
AtmosphereArgon; DMF previously degassed
Temperatureroom temperature
Time8
Work-upSolvent removed to dryness; residue washed several times with dichloromethane; recrystallised from THF/DMF/H2O/n-hexane.
Scalability contextSmall-molecule Schlenk/solution synthesis; isolated yield 246 mg, 30%.
Show 9 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Base | K2CO3 | 120 mg, 0.86 mmol | 2 · Experimental Section - Synthesis of Compound 1 · Scheme 1 |
| Solvent | dimethylformamide (DMF), previously degassed | 15 mL | 2 · Experimental Section - Synthesis of Compound 1 · Scheme 1 |
| Metal Source | [Fe2(S2C6H2Cl2)(CO)6] | 300 mg, 0.61 mmol | 2 · Experimental Section - Synthesis of Compound 1 · Scheme 1 |
| Linker | H2S2C6H2Cl2 | 386 mg, 1.83 mmol | 2 · Experimental Section - Synthesis of Compound 1 · Scheme 1 |
| Solvent | tetrahydrofuran (THF) | Not specified | 2 · Experimental Section - Synthesis of Compound 1 · Scheme 1 |
| Solvent | DMF | a few drops | 2 · Experimental Section - Synthesis of Compound 1 · Scheme 1 |
| Additive | H2O | Not specified | 2 · Experimental Section - Synthesis of Compound 1 · Scheme 1 |
| Solvent | n-hexane | Not specified | 2 · Experimental Section - Synthesis of Compound 1 · Scheme 1 |
| Solvent | dichloromethane | several washes | 2 · Experimental Section - Synthesis of Compound 1 · Scheme 1 |