Synthesis · Flexible Smart Wearable Co@C@Carbon Fabric for Efficient Electromagnetic Shielding, Thermal Therapy, and Human Movement Monitoring

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Vague recipeSource: Main

Route 1: Other

2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF

Atmospherenot specified in comparison sentence; likely analogous furnace conditions

Temperature700, 800, 900, 1000

Substrate orientationcotton non-woven fabric

Activationheating/carbonisation

Scalability contextControl preparation is summarised briefly; SI may contain full details.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	cotton non-woven fabric	Not specified	2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF

Complete recipeSource: Main

Route 2: Other

2 (11826) · 2.2.2 Synthesis of Co@C-Loaded Carbon Fiber Cloth

Metal precursorsZIF-67@CF containing Co nodes

Linker precursors2-MIM in ZIF-67@CF

AtmosphereAr gas

Temperature700, 800, 900, 1000

Time2

Substrate orientationZIF-67@CF placed in porcelain boat in tubular furnace

Oxidant / reductantpyrolytic carbon from imidazole ligand reduces Co2+ to metallic Co

Work-upnaturally cooled to room temperature

Activationcalcination under Ar at 5 C/min

Scalability contextBatch tubular-furnace annealing of textile samples; checked SI contains supporting figures but no additional furnace recipe details.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	ZIF-67@CF	Not specified	2 (11826) · 2.2.2 Synthesis of Co@C-Loaded Carbon Fiber Cloth
Other	Ar gas	Not specified	2 (11826) · 2.2.2 Synthesis of Co@C-Loaded Carbon Fiber Cloth

Complete recipeSource: Main

Route 3: Other

2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF

Metal precursorsCo-CCF series

Solventsn-hexane

AdditivesPDMS main agent, PDMS curing agent

Atmosphereair; not otherwise specified

Temperature80

Time0.033 soak; 4 drying

Substrate orientationCo-CCF soaked in diluted PDMS solution

Work-upsoaked for 2 min, transferred to 80 C oven, dried 4 h

Scalability contextShort dip/soak encapsulation and oven drying; checked SI contains supporting figures but no additional PDMS curing details.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Co-CCF	Not specified	2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF
Additive	PDMS main agent	5 g	2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF
Additive	PDMS curing agent	0.5 g	2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF
Solvent	n-hexane	PDMS:n-hexane weight ratio 1:2	2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF

Vague recipeSource: Main

Route 4: Other

2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF

Solventsn-hexane

AdditivesPDMS main agent; PDMS curing agent

Atmosphereair; not otherwise specified

Temperature80

Time0.033 soak; 4 drying

Substrate orientationCF control soaked in diluted PDMS solution

Work-upPDMS encapsulation analogous to Co-CCF route

Scalability contextControl preparation references the same PDMS encapsulation but does not repeat all details.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	CF-700/800/900/1000	Not specified	2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF
Additive	PDMS	Not specified	2 (11826) · 2.2.3 PDMS Encapsulation of Co-CCF

Complete recipeSource: Main

Route 5: Other

2 (11826) · 2.2.1 Synthesis of ZIF-67@Cotton Fabric

Metal precursorsCo(NO3)2.6H2O, 1.164 g

Linker precursors2-methylimidazole (2-MIM), 1.314 g

Solventsmethanol, 50 mL for each precursor solution

Atmosphereambient; not further specified

Temperature25; drying at 60

Time24; drying 6

Substrate orientationcotton non-woven fabric placed vertically

Work-upaged at 25 C for 24 h, then dried in oven at 60 C for 6 h

Scalability contextMain article describes a simple in situ growth on cotton fabric; checked SI contains supporting figures but no additional recipe details.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Co(NO3)2.6H2O	1.164 g	2 (11826) · 2.2.1 Synthesis of ZIF-67@Cotton Fabric
Linker	2-methylimidazole (2-MIM)	1.314 g	2 (11826) · 2.2.1 Synthesis of ZIF-67@Cotton Fabric
Solvent	methanol	50 mL for each solution	2 (11826) · 2.2.1 Synthesis of ZIF-67@Cotton Fabric
Other	cotton non-woven fabric	Not specified	2 (11826) · 2.2.1 Synthesis of ZIF-67@Cotton Fabric