Partial recipeSource: Main
Route 1: Solvothermal
9916 · Catalyst synthesis
Metal precursorsStoichiometric amounts of NiCl2.6H2O and FeCl3.6H2O; Fe/Ni varied for x = 0, 0.14, 0.20, 0.33, 0.50, 1
Linker precursors1,3,5-benzenetricarboxylic acid (H3BTC), same molar ratio as total metal cations
Solvents40 mL N,N-dimethylformamide (DMF); anhydrous ethanol for purification
AtmosphereNot specified for solvothermal step; vacuum during final drying
Temperature150; activation/drying 80
Time24; activation/drying 24
Work-upCool to room temperature; collect pale green products; purify three times with anhydrous ethanol solutions.
ActivationKeep light green precipitate for 24 h at 80 C under vacuum conditions.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | NiCl2.6H2O | stoichiometric amounts varied by x | 9916 · Catalyst synthesis |
| Metal Source | FeCl3.6H2O | stoichiometric amounts varied by x | 9916 · Catalyst synthesis |
| Linker | 1,3,5-benzene tricarboxylic acid (H3BTC) | same molar ratio as total metal cations | 9916 · Catalyst synthesis |
| Solvent | N,N-dimethylformamide (DMF) | 40 mL | 9916 · Catalyst synthesis |
| Solvent | anhydric ethanol solutions | used three times for purification | 9916 · Catalyst synthesis |