Spectroscopy — Synthesis, Characterization, and Catalytic Performance of a New Heterobimetallic Y/Tb Metal-Organic Framework with High Catalytic Activity

2 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Y/Tb-MOF bulk catalyst powder/crystals · Powder

Nicolet 6700 FTIR; KBr pellets; 400-4000 cm-1.

Context: pristine target framework
Measurement source: p003 and p022 / S3, S22 · General experimental information; FTIR analysis · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
carboxylate/asymmetric/aromatic band	1428	—	—	Text Rounded Reported	p004-p005 / 26552-26553 · Synthesis and Characterization · Figure S13
carboxylate/asymmetric/aromatic band	1508	—	—	Text Rounded Reported	p004-p005 / 26552-26553 · Synthesis and Characterization · Figure S13
carboxylate/asymmetric/aromatic band	1597	—	—	Text Rounded Reported	p004-p005 / 26552-26553 · Synthesis and Characterization · Figure S13
carboxylate/asymmetric/aromatic band	1656	—	—	Text Rounded Reported	p004-p005 / 26552-26553 · Synthesis and Characterization · Figure S13
M-O/M-N assigned low-frequency band	658	—	—	Text Rounded Reported	p004-p005 / 26552-26553 · Synthesis and Characterization · Figure S13
NH/OH broad band	3191	—	—	Text Rounded Reported	p004-p005 / 26552-26553 · Synthesis and Characterization · Figure S13
symmetric carboxylate stretching	1392	—	—	Text Rounded Reported	p004-p005 / 26552-26553 · Synthesis and Characterization · Figure S13

Y/Tb-MOF bulk catalyst powder/crystals · Powder

ICP-MS on Perkin Elmer NexION 300D; elemental analysis reported as calculated/found CHN.

Context: pristine target framework
Measurement source: p008 / S8 · Chemical characterization of compounds · Tables S1-S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
elemental analysis C found	33.05	—	—	SI Table Exact Reported	p008 / S8 · Chemical characterization of compounds · Tables S1-S2
elemental analysis H found	2.53	—	—	SI Table Exact Reported	p008 / S8 · Chemical characterization of compounds · Tables S1-S2
elemental analysis N found	6.29	—	—	SI Table Exact Reported	p008 / S8 · Chemical characterization of compounds · Tables S1-S2
Tb content	125.83 +/- 0.43	—	+/- 0.43	SI Table Exact Reported	p008 / S8 · Chemical characterization of compounds · Tables S1-S2
Y content	149.08 +/- 0.75	—	+/- 0.75	SI Table Exact Reported	p008 / S8 · Chemical characterization of compounds · Tables S1-S2
Y/Tb molar ratio	3.55/1.677	—	—	SI Table Exact Reported	p008 / S8 · Chemical characterization of compounds · Tables S1-S2