Measurement evidence
In Situ Construction of Amide-Functionalized 2D Conjugated Metal-Organic Frameworks with Multiple Active Sites for High-Performance Potassium-Ion Batteries · Su X., Cheng L., Yan X. et al. · Journal of the American Chemical Society · 2025 · 18338-18348
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Super P + PVDF blank electrode · Electrode
Super P + PVDF on carbon-coated aluminium foil; 0.5 mV s-1 CV and 0.2 A g-1 GCD
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Super P/PVDF contribution | minimal impact on performance assessment | — | — | Qualitative Qualitative | p003 / 18341 · Electrochemical Characterization · Figure S23 |
Cu-HBB-MOF cathode electrode in CR2025 potassium half-cell · Electrode
CR2025 K half-cell; 1.0-3.8 V vs K/K+; 0.5 mV s-1; optimal electrolyte 1 M KPF6 in DME
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| CV oxidation peak pair 1 oxidation | 3.04 V / 2.95 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3a |
| CV oxidation peak pair 1 reduction | 3.04 V / 2.95 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3a |
| CV pair 2 oxidation | 2.43 V / 2.11 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3a |
| CV pair 2 reduction | 2.43 V / 2.11 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3a |
| CV pair 3 oxidation | 1.90 V / 1.29 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3a |
| CV pair 3 reduction | 1.90 V / 1.29 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3a |
Cu-Salphen-MOF cathode electrode in CR2025 potassium half-cell · Electrode
CR2025 K half-cell; 1.0-3.8 V vs K/K+; 0.5 mV s-1
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| CV pair 1 oxidation | 3.56 V / 2.54 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure S25 |
| CV pair 1 reduction | 3.56 V / 2.54 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure S25 |
| CV pair 2 oxidation | 2.38 V / 1.24 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure S25 |
| CV pair 2 reduction | 2.38 V / 1.24 V | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure S25 |
Cu-HBB-MOF cathode electrode in CR2025 potassium half-cell · Electrode
CV curves at 0.6, 0.8, 1.0, 1.2 and 1.4 mV s-1; b-value and capacitive contribution analysis
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| b value O1 | bO1 = 0.71 | — | — | Text Exact Reported | p006 / 18343 · Electrochemical Characterization · Figure 3g |
| b value O2 | bO2 = 0.87 | — | — | Text Exact Reported | p006 / 18343 · Electrochemical Characterization · Figure 3g |
| b value R1 | bR1 = 0.96 | — | — | Text Exact Reported | p006 / 18343 · Electrochemical Characterization · Figure 3g |
| b value R2 | bR2 = 0.84 | — | — | Text Exact Reported | p006 / 18343 · Electrochemical Characterization · Figure 3g |
| Cu-Salphen-MOF b value O1 | bO1 = 0.78 | — | — | Text Exact Reported | p006 / 18343 · Electrochemical Characterization · Figure S31 |
| Cu-Salphen-MOF b value R1 | bR1 = 0.89 | — | — | Text Exact Reported | p006 / 18343 · Electrochemical Characterization · Figure S31 |
| Cu-HBB-MOF capacitive contribution at 0.6 mV s-1 | 69.1% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figures 3h and S30b |
| Cu-HBB-MOF capacitive contribution at 0.8 mV s-1 | 70.9% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figures 3h and S30b |
| Cu-HBB-MOF capacitive contribution at 1.0 mV s-1 | 72.0% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figures 3h and S30b |
| Cu-HBB-MOF capacitive contribution at 1.2 mV s-1 | 75.2% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figures 3h and S30b |
| Cu-HBB-MOF capacitive contribution at 1.4 mV s-1 | 77.3% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figures 3h and S30b |
| Cu-Salphen-MOF capacitive contribution at 0.6 mV s-1 | 36.2% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figure S31c |
| Cu-Salphen-MOF capacitive contribution at 0.8 mV s-1 | 41.9% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figure S31c |
| Cu-Salphen-MOF capacitive contribution at 1.0 mV s-1 | 45.0% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figure S31c |
| Cu-Salphen-MOF capacitive contribution at 1.2 mV s-1 | 48.5% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figure S31c |
| Cu-Salphen-MOF capacitive contribution at 1.4 mV s-1 | 51.7% | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figure S31c |
Cu-HBB-MOF cathode electrode in CR2025 potassium half-cell · Electrode
100 kHz to 0.1 Hz; Nyquist analysis
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Rct Cu-HBB-MOF | approximately 10 ohm | — | — | Text Approximate | p006 / 18343 · Electrochemical Characterization · Figures 3f and S29 |
| Rct Cu-HBB-MOF after 100 cycles | increased from 10 to 13 ohm | — | — | Text Rounded Reported | p006 / 18343 · Electrochemical Characterization · Figures 3f and S29 |
| Rct Cu-Salphen-MOF | approximately 30 ohm | — | — | Text Approximate | p006 / 18343 · Electrochemical Characterization · Figures 3f and S29 |
Cu-HBB-MOF cathode electrode in CR2025 potassium half-cell · Electrode
CR2025 K half-cell, voltage range 1.00-3.80 V; 1 M KPF6 in DME
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| reversible specific capacity at 0.1 A g-1Marked as a best value within this paper | 264.5 mAh g-1 at 0.1 A g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figures S26-S27 |
| discharge specific capacity at 0.2 A g-1Marked as a best value within this paper | 228.1 mAh g-1 at 0.2 A g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure S28; Table S8 |
| capacity after 100 cycles at 1.0 A g-1 | 167.6 mAh g-1 after 100 cycles at 1.0 A g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3c |
| capacity decay per cycleMarked as a best value within this paper | 0.011% per cycle | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3d |
| Coulombic efficiencyMarked as a best value within this paper | 100% | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3d |
| long-cycle retained capacityMarked as a best value within this paper | 103.6 mAh g-1 after 2500 cycles at 5.0 A g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3d |
| rate capacity at 0.5 A g-1 | 201.5 mAh g-1 at 0.5 A g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3e |
| rate capacity at 10.0 A g-1 | 127.8 mAh g-1 at 10.0 A g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3e |
| capacity recovered after returning to 0.5 A g-1 | 201.8 mAh g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3e |
| theoretical specific capacity | 271.0 mAh g-1 | — | — | Text Rounded Reported | S30-S31 · Electrochemical Characterization · Figure S26 |
Cu-Salphen-MOF cathode electrode in CR2025 potassium half-cell · Electrode
CR2025 K half-cell, voltage range 1.00-3.80 V
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| discharge specific capacity at 0.2 A g-1 | 149.2 mAh g-1 at 0.2 A g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure S28a |
| capacity after 100 cycles at 1.0 A g-1 | 72.9 mAh g-1 after 100 cycles at 1.0 A g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figure 3c |
| Cu-Salphen-MOF rate capacity point 1 | 117.9 mAh g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figures 3e and S28c |
| Cu-Salphen-MOF rate capacity point 2 | 98.5 mAh g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figures 3e and S28c |
| Cu-Salphen-MOF rate capacity point 3 | 80.3 mAh g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figures 3e and S28c |
| Cu-Salphen-MOF rate capacity point 4 | 57.8 mAh g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figures 3e and S28c |
| Cu-Salphen-MOF rate capacity point 5 | 40.8 mAh g-1 | — | — | Text Rounded Reported | p005 / 18342 · Electrochemical Characterization · Figures 3e and S28c |
Cu-HBB-MOF cathode electrode in CR2025 potassium half-cell · Electrode
GITT-derived K+ diffusion coefficient using Fick's second law
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| K+ diffusion coefficient upper bound, Cu-HBB-MOF | 10^-10 to 10^-9 cm2 s-1 | — | — | Text Range | p006 / 18343 · Electrochemical Characterization · Figure S32 |
| K+ diffusion coefficient lower bound, Cu-HBB-MOF | 10^-10 to 10^-9 cm2 s-1 | — | — | Text Range | p006 / 18343 · Electrochemical Characterization · Figure S32 |
| K+ diffusion coefficient upper bound, Cu-Salphen-MOF | 10^-11 to 10^-10 cm2 s-1 | — | — | Text Range | p006 / 18343 · Electrochemical Characterization · Figure S32 |
| K+ diffusion coefficient lower bound, Cu-Salphen-MOF | 10^-11 to 10^-10 cm2 s-1 | — | — | Text Range | p006 / 18343 · Electrochemical Characterization · Figure S32 |