Blocked Missing Si recipeSource: Missing SI
Route 1: Unknown
p002 · Results and discussion
Synthesis evidence
Enhancement in electrical conductivity of a porous indium based metal-organic framework upon I2 uptake: Combined experimental and theoretical investigations
Mani P., Mandal N., Roopesh M. et al. · Journal of Materials Chemistry C · 2020 · 4836-4842
5 structured synthesis routes
Completeness describes how fully the route could be reconstructed from the main article and supporting information.
Partial recipeSource: Main
Route 2: Other
p002 · Results and discussion · Fig. S3; Fig. S4
Metal precursorscompound 1; indium already in framework
Linker precursorscompound 1; TDC already in framework
Solventsiodine solution, solvent not explicitly restated in this sentence; likely cyclohexane from preceding route
Additivesiodine, 0.1 M
Atmospherevacuum drying; activation atmosphere not restated
Timeabout 10 days uptake
Oxidant / reductantI2 guest molecule
Work-upSeparated by filtration and dried under vacuum.
ActivationCompound 1 was activated before iodine dispersion; activation conditions not repeated in this paragraph.
Show 2 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Other | compound 1 | Not specified | p002 · Results and discussion · Fig. S3; Fig. S4 |
| Additive | iodine solution | 0.1 M | p002 · Results and discussion · Fig. S3; Fig. S4 |
Partial recipeSource: Main
Route 3: Other
p002 · Results and discussion · Fig. 1b; Fig. S1
Metal precursorscompound 1; indium already in framework
Linker precursorscompound 1; TDC already in framework
Solventscyclohexane
Additivesiodine guest, 0.1 M in cyclohexane
Atmospherevacuum during activation and drying; uptake atmosphere not specified
Temperature80 activation
Time5 activation; uptake sampled over time intervals
Oxidant / reductantI2 guest molecule
Work-upAt each interval crystals separated by filtration, washed with cyclohexane and dried under vacuum.
Activationcompound 1 activated at 80 deg C for 5 h under vacuum
Scalability contextReported on 100 mg activated MOF.
Show 3 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Other | compound 1 (activated) | 100 mg | p002 · Results and discussion · Fig. 1b; Fig. S1 |
| Additive | iodine | 0.1 M in cyclohexane | p002 · Results and discussion · Fig. 1b; Fig. S1 |
| Solvent | cyclohexane | Not specified | p002 · Results and discussion · Fig. 1b; Fig. S1 |
Partial recipeSource: SI
Route 4: Other
p004 · Figure S1 caption and text · Fig. S1
Metal precursorscompound 1; indium already in framework
Linker precursorscompound 1; TDC already in framework
Solventsnone stated for vapour exposure
Additivesiodine vapours
Atmosphereclosed glass flask with iodine vapours
Timeabout 168 h for 7 day uptake point; graph extends to about 260 h
Oxidant / reductantI2 vapour guest molecule
Work-upIncremental weight measured at each time interval; no washing/drying workup described in SI passage.
Scalability contextReported on about 100 mg compound 1.
Show 2 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Other | compound 1 | about 100 mg | p004 · Figure S1 caption and text · Fig. S1 |
| Additive | iodine vapors | Not specified | p004 · Figure S1 caption and text · Fig. S1 |
Partial recipeSource: Main
Route 5: Other
p003 · Results and discussion · Fig. 4
Solventscyclohexane
Timerelease monitored over about 15 days
Work-upI2@1 dispersed in cyclohexane; release monitored by UV-visible spectroscopy.
Scalability context10 mg I2@1 in 4 mL cyclohexane for spectroscopy; Fig. 4 caption also mentions 50 mg in 4 mL for photographs.
Show 2 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Other | I2@1 | about 10 mg | p003 · Results and discussion · Fig. 4 |
| Solvent | cyclohexane | 4 mL | p003 · Results and discussion · Fig. 4 |