Wang Z., Sun B., Liao J. et al. · International Journal of Biological Macromolecules · 2024 · 127989
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Room-temperature densification of the EC-MOF@TOW bulk yields flexible ultrathin membranes with tensile strength above 180 MPa and stable conductivity/wetting under deformation.
Caveat: Long-cycle mechanical fatigue and full wearable-device tests are not reported in the main text.
p009 / journal page 9 · 4. Conclusion · Linked to 5 structured results
Further comprehensive research is necessary to optimise whole-supercapacitor performance using EC-MOF@TOW membrane electrodes for practical applications.
Caveat: This is an author-stated limitation.
p009 / journal page 9 · 3.3 Electrochemical properties of EC-MOF@TOW membrane · Table S3 · Linked to 2 structured results
The 50%-NiCAT@TOW membrane electrode outperforms NiCAT powder because high conductivity, hierarchical pores and 1D NiCAT channels lower ion/electron transport resistance.
Caveat: Only preliminary three-electrode performance is reported; full symmetric solid supercapacitor optimisation is deferred.
p009 / journal page 9 · 3.3 Electrochemical properties of EC-MOF@TOW membrane · Fig. 6e-f · Linked to 5 structured results
The hydrophobicity of 50%-NiCAT@TOW is attributed to the continuous rough NiCAT covering layer on the TOW surface.
Caveat: The authors explicitly state that the intrinsic hydrophobicity of the NiCAT layer and contributing factors require further investigation.
p008 / journal page 8 · 3.2 Properties characterization of EC-MOF@TOW membrane · Fig. 5c · Linked to 3 structured results
COO- groups introduced by TEMPO oxidation immobilise Ni2+ or Cu2+ through electrostatic attraction, enabling uniform and continuous EC-MOF growth on wood cellulose fibres.
Caveat: CuCAT-specific bonding evidence is in missing supporting Fig. S5.
p004 / journal page 4 · 3.1 Preparation of EC-MOF@TOW membrane · Linked to 3 structured results
Higher Ni2+ pretreatment concentration increases NiCAT@TOW conductivity by providing more nucleation sites, reducing EC-MOF grain boundaries and particle spacing, and forming interconnected nanowire transport pathways.
Caveat: Mechanistic claim is inferred from morphology and conductivity trends; no direct grain-boundary metric is reported.
p008 / journal page 8 · 3.3 Electrochemical properties of EC-MOF@TOW membrane · Fig. 6a-b · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| CuCATBrowse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu-HHTP catecholate frameworkCu(II) · 2,3,6,7,10,11-hexahydroxytriphenylene hydrate (HHTP) | 2D · PristineCopper catecholate EC-MOF analogue grown on TOW; bonding and properties are mainly discussed in missing SI. | p004 / journal page 4 · 3.1 Preparation of EC-MOF@TOW membrane |
| CuCAT@TOW composite membrane | CuCAT on TEMPO-oxidised wood cellulose scaffoldCu(II) in CuCAT and Cu(II) bridge sites · HHTP in CuCAT; carboxylated cellulose in TOW scaffold | 2D · CompositeComposite membrane containing CuCAT grown on TOW; continuous growth is reported from SEM/EDX in missing SI. | p005 / journal page 5 · 3.1 Preparation of EC-MOF@TOW membrane · Fig. S3 |
| NiCATBrowse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni-HHTP catecholate frameworkNi(II) · 2,3,6,7,10,11-hexahydroxytriphenylene hydrate (HHTP) | 2D · Pristine2D hexagonal nickel catecholate layers packed along the c-axis in an ABAB arrangement, with 1D channels along the c-axis. | p005 / journal page 5 · 3.1 Preparation of EC-MOF@TOW membrane · Fig. 2d |
| NiCAT@TOW composite membraneBrowse family: Ni₃(HHTP)₂ / Ni–HHTP | NiCAT on TEMPO-oxidised wood cellulose scaffoldNi(II) in NiCAT; Ni(II) bridge sites at the TOW interface · HHTP in NiCAT; carboxylated cellulose in TOW scaffold | 2D · CompositeComposite membrane containing continuous NiCAT nanolayers/nanowires grown on porous TEMPO-oxidised balsa wood scaffold. | p004 / journal page 4 · 3.1 Preparation of EC-MOF@TOW membrane |
| TEMPO-oxidised balsa wood scaffold (TOW) | carboxylated cellulose-rich balsa wood scaffoldcellulose hydroxyl/carboxylate groups | unknown · Model SystemPorous, aligned wood cellulose scaffold bearing COO- groups after delignification and TEMPO oxidation. | p004 / journal page 4 · 3.1 Preparation of EC-MOF@TOW membrane · Fig. 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| 50%-CuCAT@TOW membraneresearch_0672__mat__mat_cucat_tow | Thin Film · Composite Sample · Composite | CuCAT grown on TOW using the same general process as NiCAT@TOW; details in missing SITEMPO-oxidised wood scaffold | p002 / journal page 2 · 2.3 Preparation of NiCAT@TOW composite membrane |
| delignified wood (DW)research_0672__mat__mat_tow | Thin Film · Model System · Model | balsa wood delignified in NaClO2/acetate buffer and stored in ethanolbalsa wood · 1 mm starting wood thickness | p002 / journal page 2 · 2.2 Preparation of TEMPO oxidized Balsa wood substrate (TOW) |
| 50%-Ni2+-TOWresearch_0672__mat__mat_tow | Thin Film · Model System · Composite | TOW pretreated with 50 wt% Ni(NO3)2.6H2O without HHTP-derived NiCAT growthTEMPO-oxidised wood scaffold | p005 / journal page 5 · 3.1 Preparation of EC-MOF@TOW membrane · Fig. 3d |
| 50%-NiCAT@DWresearch_0672__mat__mat_nicat_tow | Thin Film · Composite Sample · Composite | DW without TEMPO oxidation but treated with 50% Ni2+ before attempted NiCAT growthdelignified wood without TEMPO oxidation | p008 / journal page 8 · 3.3 Electrochemical properties of EC-MOF@TOW membrane · Fig. 6b |
| NiCAT powderresearch_0672__mat__mat_nicat | Powder · Pristine Control · Pristine Framework | hydrothermally synthesised NiCAT crystals/powder | p005 / journal page 5 · 3.1 Preparation of EC-MOF@TOW membrane · Fig. 2f; Fig. 3 |
| NiCAT powder electroderesearch_0672__mat__mat_nicat | Electrode · Pristine Control · Pristine Framework | NiCAT powder mixed with polymer binder and coated onto carbon papercarbon paper current collector | p009 / journal page 9 · 3.3 Electrochemical properties of EC-MOF@TOW membrane · Fig. 6e-f |
| 1%-NiCAT@TOW membraneresearch_0672__mat__mat_nicat_tow | Thin Film · Composite Sample · Composite | TOW pretreated with 1 wt% Ni(NO3)2.6H2O, NiCAT grown in situ, humidified and pressedTEMPO-oxidised wood scaffold | p002 / journal page 2 · 2.3 Preparation of NiCAT@TOW composite membrane · Fig. 6a |
| 10%-NiCAT@TOW membraneresearch_0672__mat__mat_nicat_tow | Thin Film · Composite Sample · Composite | TOW pretreated with 10 wt% Ni(NO3)2.6H2O, NiCAT grown in situ, humidified and pressedTEMPO-oxidised wood scaffold | p002 / journal page 2 · 2.3 Preparation of NiCAT@TOW composite membrane · Fig. 6a |
| 5%-NiCAT@TOW membraneresearch_0672__mat__mat_nicat_tow | Thin Film · Composite Sample · Composite | TOW pretreated with 5 wt% Ni(NO3)2.6H2O, NiCAT grown in situ, humidified and pressedTEMPO-oxidised wood scaffold | p002 / journal page 2 · 2.3 Preparation of NiCAT@TOW composite membrane · Fig. 6a |
| 50%-NiCAT@TOW membraneresearch_0672__mat__mat_nicat_tow | Thin Film · Target Sample · Composite | TOW pretreated with 50 wt% Ni(NO3)2.6H2O, NiCAT grown in situ, humidified at 98% RH and pressed at 10 MPaTEMPO-oxidised wood scaffold · about 0.3 mm | p004 / journal page 4 · 3.1 Preparation of EC-MOF@TOW membrane · Fig. 2a-c |
| NiCAT@TOW without 50%-Ni2+ pretreatmentresearch_0672__mat__mat_nicat_tow | Thin Film · Composite Sample · Composite | TOW scaffold without 50%-Ni2+ treatment before attempted NiCAT growthTEMPO-oxidised wood scaffold | p008 / journal page 8 · 3.3 Electrochemical properties of EC-MOF@TOW membrane · Fig. 6b |
| TOW membraneresearch_0672__mat__mat_tow | Thin Film · Model System · Model | compressed TOW scaffold at room temperaturecompressed TOW scaffold · about 0.29 mm from Fig. 1g visual label | p004 / journal page 4 · 3.1 Preparation of EC-MOF@TOW membrane · Fig. 1e-g |
| TOW scaffoldresearch_0672__mat__mat_tow | Thin Film · Model System · Model | delignified wood oxidised by TEMPO/NaClO/NaBr and vacuum freeze-driedbalsa wood cellulose scaffold · 20 mm x 15 mm x 1 mm oxidised samples before compression | p002 / journal page 2 · 2.2 Preparation of TEMPO oxidized Balsa wood substrate (TOW) |