Other — Diamagnetic Carrier-Doping-Induced Continuous Electronic and Magnetic Crossover in One-Dimensional Coordination Polymers

Measurement evidence

Other

Diamagnetic Carrier-Doping-Induced Continuous Electronic and Magnetic Crossover in One-Dimensional Coordination Polymers · Shen Y., Cui M., Li G. et al. · Journal of the American Chemical Society · 2024 · 35367-35376

3 measurement groups · 27 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

AC magnetic susceptibility by SQUID

all Cu-doping-ratio powders · Powder

Frequency range 1-1500 Hz; zero field; spin relaxation fitted.

Context
Series slow magnetization relaxation
Measurement source
8 · Physical Techniques · Figure 5; Table 1; Figure S13
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu0.95Co0.05 spin relaxation not determinedsignal of chi double-prime is too weak to determine tauText
Qualitative
6 · Magnetic Interactions Crossover · Figure S13
Cu0.0Co1.0 spin reversal energy UeffMarked as a best value within this paperUeff = 560(3) K(3) KText
Exact Reported
5-6 · Magnetic Interactions Crossover · Table 1
Cu0.05Co0.95 spin reversal energy UeffUeff = 475(20) K(20) KText
Exact Reported
5-6 · Magnetic Interactions Crossover · Table 1
Cu0.3Co0.7 spin reversal energy UeffUeff = 375(4) K(4) KText
Exact Reported
5-6 · Magnetic Interactions Crossover · Table 1
Cu0.5Co0.5 spin relaxation UeffUeff = 34.4(2) K(2) KText
Exact Reported
6 · Magnetic Interactions Crossover · Table 1
Cu0.75Co0.25 spin relaxation UeffUeff = 1.6(1) K(1) KText
Exact Reported
6 · Magnetic Interactions Crossover · Table 1
Cu0.9Co0.1 spin relaxation UeffUeff = 1.612 KText
Exact Reported
6 · Magnetic Interactions Crossover · Table 1
Cu0.0Co1.0 tau0tau0 = 2.4(3) x 10^-10 s(3) x 10^-10 sText
Exact Reported
5-6 · Magnetic Interactions Crossover · Table 1
Cu0.05Co0.95 tau0tau0 = 4.9(4) x 10^-10 s(4) x 10^-10 sText
Exact Reported
5-6 · Magnetic Interactions Crossover · Table 1
Cu0.3Co0.7 tau0tau0 = 3.9(6) x 10^-9 s(6) x 10^-9 sText
Exact Reported
5-6 · Magnetic Interactions Crossover · Table 1

SQUID DC magnetic susceptibility

all Cu-doping-ratio powders · Powder

Polycrystalline samples, 2-300 K; Curie-Weiss fitting and chiT values.

Temperature
2-300
Context
Series magnetic crossover
Measurement source
8 · Physical Techniques · Figures 4, S7, S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu0.5Co0.5 blocking temperatureTB = 6 KSI Table
Exact Reported
18 · Figure S11 caption · Figure S11
Blocking temperature for Cu0.0Co1.0, Cu0.05Co0.95, Cu0.3Co0.7Marked as a best value within this paperTB = 21.5 KSI Table
Exact Reported
18 · Figure S11 caption · Figure S11
Blocking temperature for Cu0.75Co0.25, Cu0.9Co0.1, Cu0.95Co0.05TB = 0 KSI Table
Exact Reported
18 · Figure S11 caption · Figure S11
Cu0.0Co1.0 chiT at 300 K3.44 cm3 K mol-1Text
Exact Reported
4 · Magnetic Interactions Crossover · Table S5
Cu0.05Co0.95 chiT at 300 K3.30 cm3 K mol-1Text
Exact Reported
4 · Magnetic Interactions Crossover · Table S5
Cu0.3Co0.7 chiT at 300 K2.43 cm3 K mol-1Text
Exact Reported
4 · Magnetic Interactions Crossover · Table S5
Cu0.5Co0.5 chiT at 300 K1.64 cm3 K mol-1Text
Exact Reported
4 · Magnetic Interactions Crossover · Table S5
Cu0.75Co0.25 chiT at 300 K0.80 cm3 K mol-1Text
Exact Reported
4 · Magnetic Interactions Crossover · Table S5
Cu0.9Co0.1 chiT at 300 K0.33 cm3 K mol-1Text
Exact Reported
4 · Magnetic Interactions Crossover · Table S5
Cu0.95Co0.05 chiT at 300 K0.17 cm3 K mol-1Text
Exact Reported
4 · Magnetic Interactions Crossover · Table S5
Cu0.0Co1.0 Curie-Weiss temperature+76(3) K(3) KText
Exact Reported
4 · Magnetic Interactions Crossover · Figure 4a,b
Cu0.05Co0.95 Curie-Weiss temperature+67(2) K(2) KText
Exact Reported
4 · Magnetic Interactions Crossover · Figure 4a,b
Cu0.3Co0.7 Curie-Weiss temperature+40(2) K(2) KText
Exact Reported
4 · Magnetic Interactions Crossover · Figure 4a,b
Cu0.5Co0.5 Curie-Weiss temperature0(1) K(1) KText
Exact Reported
4 · Magnetic Interactions Crossover · Figure 4b
Cu0.75Co0.25 Curie-Weiss temperature-18(1) K(1) KText
Exact Reported
5 · Magnetic Interactions Crossover · Figure 4b
Cu0.9Co0.1 Curie-Weiss temperature-60(3) K(3) KText
Exact Reported
5 · Magnetic Interactions Crossover · Figure 4b
Cu0.95Co0.05 Curie-Weiss temperature-148(10) K(10) KText
Exact Reported
5 · Magnetic Interactions Crossover · Figure 4b

Field-dependent magnetization M-H

all Cu-doping-ratio powders · Powder

M-H curves at 2 K in main figure and multiple temperatures in SI.

Temperature
2
Context
Series magnetic hysteresis
Measurement source
5 · Cu-Doping Dependence of Magnetic Interactions · Figure 4d; Figure S12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource