Chen S.-C., Zhang Z.-H., Huang K.-L. et al. · CrystEngComm · 2013 · 9613-9622
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Complex 1 shows the strongest blue solid-state emission among complexes 1-4 and is suggested as potentially useful for functional materials.
Caveat: Application relevance is speculative; no device or performance testing is reported.
p010 · Photophysical studies · Fig. 8 · Linked to 1 structured result
The only electrical-transport-like measurement is molar electrical conductivity of aqueous solutions of 5 and 6; no solid-state electronic conductivity, thermoelectric, device, electrochemical or gas-sorption measurements are reported for the frameworks.
Caveat: Conductivity reflects dissociated solution species, not framework charge transport.
p002-p003 · Materials and general methods; Syntheses and solution characterization · Linked to 2 structured results
PXRD comparisons indicate the bulk synthesised materials and as-grown single crystals are homogeneous for complexes 1-6, despite minor unindexed or broadened lines.
Caveat: XRPD patterns are shown graphically in SI Fig. S8; the text acknowledges a few un-indexed diffraction lines and slight broadening.
p009 · XRPD results · Fig. S8 · Linked to 6 structured results
ESI-MS and molar conductivity support dissociation of the original polymeric structures of 5 and 6 into ionic species in water.
Caveat: The species assignments are based on ESI-MS and conductivity rather than direct structural measurement in solution.
p003 · Syntheses and solution characterization · Fig. 1 · Linked to 4 structured results
Different alkali-metal ions regulate the assembly of Cd/Zn perhalogenated terephthalate coordination polymers, producing different 1D/3D architectures.
Caveat: Mechanistic conclusion is based on comparative products under related room-temperature evaporation conditions.
p008 · Effect of alkali-metal ions · Table 2 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Complex 1 | [Cd3(BDC-F4)3(DMF)2(MeOH)6]nCd(II) nodes; CdO7 and CdO6 coordination environments · 2,3,5,6-tetrafluoroterephthalate (BDC-F4); DMF; methanol | 3D · PristineOpen 3D Cd(II) coordination framework; CdSO4 (cds) net; 3-nodal (3,4)-connected | p001 · Abstract; Crystal structures |
| Complex 2 | [Cd(BDC-F4)(DMF)2(H2O)2]nCd(II) mono-metal CdO6 octahedral centres · 2,3,5,6-tetrafluoroterephthalate (BDC-F4); DMF; water | 1D · Pristine1D linear Cd(II) coordination chain | p001 · Abstract; Crystal structures |
| Complex 3 | [Zn2Na2(BDC-Cl4)3(DMF)4(mu2-MeOH)]nZn(II)-Na(I) tetranuclear secondary building units; ZnO4 and NaO6 · 2,3,5,6-tetrachloroterephthalate (BDC-Cl4); DMF; methanol | 3D · Pristine3D heterometallic framework based on Zn2Na2 tetranuclear clusters; pcu topology; 4-nodal (3,4,5,6)-connected | p001 · Abstract; Crystal structures |
| Complex 4 | [ZnK(BDC-Cl4)1.5(DMF)(Me2NH)]nZn(II)-K(I) tetranuclear secondary building units; ZnO3N1 and KO5Cl2 · 2,3,5,6-tetrachloroterephthalate (BDC-Cl4); DMF; dimethylamine | 3D · Pristine3D heterometallic framework based on Zn2K2 tetranuclear clusters; pcu topology; 4-nodal (3,5,6)-connected | p001 · Abstract; Crystal structures |
| Complex 5 | {[Cd4(BDC-F4)4(H2O)11].3.5H2O}nCd(II)-water double-chain; seven-coordinate Cd(II) · 2,3,5,6-tetrafluoroterephthalate (BDC-F4); coordinated and lattice water | 1D · Pristine1D Cd(II) coordination chain containing an infinite Cd(II)-H2O chain | p007 · Abstract; Crystal structures |
| Complex 6 | [Zn(H2O)6].(BDC-Cl4).4H2ODiscrete [Zn(H2O)6]2+ cation; Zn(II) octahedral aqua complex · Uncoordinated 2,3,5,6-tetrachloroterephthalate (BDC-Cl4); coordinated and lattice water | 0D · UnknownIon-paired discrete Zn(II) complex, extended only by hydrogen bonding | p007 · Abstract; Crystal structures |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Complex 1 colourless crystalsresearch_0691__mat__m1 | Single Crystal · Target Sample · Pristine Framework | as-grown crystals isolated by slow evaporation | p002-p003 · Syntheses of complexes 1-6 |
| Complex 2 colourless crystalsresearch_0691__mat__m2 | Single Crystal · Target Sample · Pristine Framework | as-grown crystals isolated by slow evaporation | p002-p003 · Syntheses of complexes 1-6 |
| Complex 3 colourless crystalsresearch_0691__mat__m3 | Single Crystal · Target Sample · Pristine Framework | as-grown crystals isolated by slow evaporation | p002-p003 · Syntheses of complexes 1-6 |
| Complex 4 colourless crystalsresearch_0691__mat__m4 | Single Crystal · Target Sample · Pristine Framework | as-grown crystals isolated by slow evaporation | p002-p003 · Syntheses of complexes 1-6 |
| Complex 5 aqueous solutionresearch_0691__mat__m5 | Unknown · Paper Level Unspecified · Unknown | aqueous solution; ESI-MS used water containing 0.5% methanol and conductivity used 10^-3 M aqueous solution at 25 deg C | p002-p003 · Materials and general methods; Syntheses and solution characterization · Fig. 1 |
| Complex 5 colourless crystalsresearch_0691__mat__m5 | Single Crystal · Target Sample · Pristine Framework | water-recrystallised crystals | p002-p003 · Syntheses of complexes 1-6 |
| Complex 6 aqueous solutionresearch_0691__mat__m6 | Unknown · Paper Level Unspecified · Unknown | aqueous solution; ESI-MS used water containing 0.5% methanol and conductivity used 10^-3 M aqueous solution at 25 deg C | p002-p003 · Materials and general methods; Syntheses and solution characterization · Fig. 1 |
| Complex 6 colourless crystalsresearch_0691__mat__m6 | Single Crystal · Target Sample · Unknown | water-recrystallised crystals | p002-p003 · Syntheses of complexes 1-6 |