Synthesis · M-008: A stable and reusable metalorganic framework with high crystallinity applied in the photocatalytic hydrogen evolution and the degradation of methyl orange

2 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

2 · Synthesis of the materials

Metal precursorszinc acetate, similar quantity to slow-evaporation synthesis: 0.56 g (0.002 mol)

Linker precursors4,4'-bipyridyl, similar quantity to slow-evaporation synthesis: 0.2 g (0.0019 mol)

Solvents3 drops methanol

Atmospherenot specified

Temperatureroom temperature grinding; 70 drying

Time0.5 dry grinding plus 0.5 after methanol addition; 24 drying

Work-upGround in a mortar for 30 min, mixed with 3 drops methanol for 30 min, then dried in an oven for 24 h at 70 C.

Activationdried at 70 C for 24 h; no separate activation reported

Scalability contextSolvent-minimised liquid-assisted mechanochemical route; no scale-up study reported.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	4,4'-bipyridyl	similar quantity to slow evaporation, 0.2 g (0.0019 mol)	2 · Synthesis of the materials
Metal Source	zinc acetate	similar quantity to slow evaporation, 0.56 g (0.002 mol)	2 · Synthesis of the materials
Solvent	methanol	3 drops	2 · Synthesis of the materials

Complete recipeSource: Main

2 · Synthesis of the materials

Metal precursorszinc acetate, 0.56 g (0.002 mol), dissolved in 5 mL water

Linker precursors4,4'-bipyridyl, 0.2 g (0.0019 mol), dissolved in 5 mL methanol

Solventsmethanol (5 mL) and water (5 mL)

Atmospherenot specified

Temperature65 reaction; 70 drying

Time24 reaction; 24 drying

Work-upSolutions mixed and heated; crystals obtained were dried in an oven for 24 h at 70 C.

Activationdried at 70 C for 24 h; no separate activation reported

Scalability contextLow-temperature solution route using water/methanol; no scale-up study reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	4,4'-bipyridyl	0.2 g (0.0019 mol) · dissolved in 5 mL methanol	2 · Synthesis of the materials
Metal Source	zinc acetate	0.56 g (0.002 mol) · dissolved in 5 mL water	2 · Synthesis of the materials
Solvent	methanol	5 mL	2 · Synthesis of the materials
Solvent	water	5 mL	2 · Synthesis of the materials