Partial recipeSource: Main
Route 1: Liquid Liquid Interface
2 · 2.2. Synthesis of CP1
Metal precursorsCd(NO3)2.4H2O (0.059 g, 0.2 mmol)
Linker precursorspdb (0.113 g, 0.4 mmol); H2aca (0.023 g, 0.2 mmol)
SolventsMeOH, H2O, 1:1 MeOH/H2O interlayer, and EtOH
AdditivesEt3N (0.021 g, 0.2 mmol) used to neutralise H2aca
Atmospherenot reported
Work-upSolutions were layered and left for a few days; light-yellow block crystals were obtained.
Activationnot reported
Scalability contextSmall-volume layering crystallisation; no scale-up discussion.
Show 7 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Cd(NO3)2.4H2O | 0.059 g, 0.2 mmol | 2 · 2.2. Synthesis of CP1 |
| Linker | pdb | 0.113 g, 0.4 mmol | 2 · 2.2. Synthesis of CP1 |
| Linker | H2aca | 0.023 g, 0.2 mmol | 2 · 2.2. Synthesis of CP1 |
| Base | Et3N | 0.021 g, 0.2 mmol | 2 · 2.2. Synthesis of CP1 |
| Solvent | MeOH | 2 mL for pdb plus 1 mL equivalent in 2 mL 1:1 MeOH/H2O layer | 2 · 2.2. Synthesis of CP1 |
| Solvent | H2O | 2 mL for Cd salt plus 1 mL equivalent in 2 mL 1:1 MeOH/H2O layer | 2 · 2.2. Synthesis of CP1 |
| Solvent | EtOH | 2 mL | 2 · 2.2. Synthesis of CP1 |