Electrochemistry Application — Aggregation-induced enhancement of pyrene-based metal-organic framework as a new electrochemiluminescence emitter for ultrasensitive detection of sulfadimethoxine

4 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CV scan-rate series with Randles-Sevcik analysis

Voltammetry

Ce-MOF/GCE · Electrode

Bare GCE and Ce-MOF/GCE measured in 5 mM K3[Fe(CN)6]/K4[Fe(CN)6] with KCl; scan rates 0.01-0.20 V s-1.

Geometry: 4 mm GCE; three-electrode electrochemical system
Context: Ce-MOF-modified electrode compared with bare GCE
Measurement source: Electrochemical property of Ce-MOF · Fig. S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Electroactive area of bare GCE	0.1369 cm2	—	—	Text Exact Reported	Electrochemical property of Ce-MOF · Fig. S3
Bare GCE Randles-Sevcik slope	Ipa = 507.70 v1/2 + 22.19	—	—	Figure Axis Exact Reported	9 · S7 Electrochemical property of Ce-MOF · Fig. S3A
Ce-MOF/GCE electroactive area relative to bare GCE	0.2125/0.1369 = 1.55	—	—	Calculated From Reported Rounded Reported	Electrochemical property of Ce-MOF · Fig. S3
Electroactive area of Ce-MOF/GCEMarked as a best value within this paper	0.2125 cm2	—	—	Text Exact Reported	Electrochemical property of Ce-MOF · Fig. S3
Ce-MOF/GCE Randles-Sevcik slopeMarked as a best value within this paper	Ipa = 788.07 v1/2 + 10.38	—	—	Figure Axis Exact Reported	9 · S7 Electrochemical property of Ce-MOF · Fig. S3B
CV scan-rate range for electroactive area	0.01-0.20 V s-1	—	reported range; numeric midpoint	Text Range	9 · S7 Electrochemical property of Ce-MOF · Fig. S3

CV and ECL mechanism study

Voltammetry

ZPM/GCE · Electrode

Bare GCE and ZPM/GCE in PBS with and without 0.05 M K2S2O8.

Geometry: modified GCE
Context: ZPM electrode with K2S2O8 co-reactant
Measurement source: 5 · 3.5 ECL mechanism of the ZPM/K2S2O8 systems · Fig. 3C-D

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
K2S2O8 boosts ZPM ECL	ZPM had a better ECL signal with the addition of K2S2O8	—	—	Text Qualitative	5 · 3.5 ECL mechanism of the ZPM/K2S2O8 systems · Fig. 3D
K2S2O8 reduction peak on bare GCE	-0.95 V	—	—	Text Exact Reported	5 · 3.5 ECL mechanism of the ZPM/K2S2O8 systems · Fig. 3C
ZPM reduction peak with K2S2O8	-1.30 V	—	—	Text Exact Reported	5 · 3.5 ECL mechanism of the ZPM/K2S2O8 systems · Fig. 3C
ZPM reduction peak in PBS	-1.55 V	—	—	Text Exact Reported	5 · 3.5 ECL mechanism of the ZPM/K2S2O8 systems · Fig. 3C

Cyclic voltammetry construction characterisation

Voltammetry

SDM/MCH/dsDNA/AuNPs/Ce-MOF/GCE with ZPM/SP tracer · Electrode

K3[Fe(CN)6]/K4[Fe(CN)6] (5 mM) containing 0.1 M KCl; curves for GCE, Ce-MOF/GCE, AuNPs/Ce-MOF/GCE, dsDNA/AuNPs/Ce-MOF/GCE, MCH/dsDNA/AuNPs/Ce-MOF/GCE and SDM/MCH/dsDNA/AuNPs/Ce-MOF/GCE.

Geometry: modified GCE
Context: stepwise composite aptasensor construction
Measurement source: 4 · 3.3 Electrochemical characterisations of ECL aptasensor · Fig. 3A

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ce-MOF and AuNPs increase peak current	peak current signal increased after Ce-MOF and AuNP modification	—	—	Text Qualitative	4 · 3.3 Electrochemical characterisations of ECL aptasensor · Fig. 3A

ECL intensity comparison

ZPM yellow precipitate powder · Powder

ECL intensities of H4TBAPy aggregations and ZPM.

Context: pristine ZPM compared with ligand aggregation control
Measurement source: 5 · 3.4 ECL performance of ZPM · Fig. 3B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ZPM ECL enhancement over H4TBAPy aggregationsMarked as a best value within this paper	roughly four times	—	—	Text Approximate	5 · 3.4 ECL performance of ZPM · Fig. 3B