Electrical Transport — Lanthanide-Hypophosphite Frameworks with Guanidinium Guest Showing High Proton Conductivity

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

complex 1 crystalline powder disc with silver glue electrodes · Pellet

room-temperature RH-dependent proton conductivity; frequency range 1 Hz to 1 MHz

Temperature: room temperature
Atmosphere: 50-97% RH
Geometry: disc pellet with conductive silver glue on both sides
Context: pristine guest-containing framework pellet
Measurement source: 3383-3384 · Proton conductivity properties; Experimental · Figure S5b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
proton conductivity of complex 1 at 50% RH, room temperature	1.61 x 10^-5 S cm^-1 at 50% RH	0.0000161 S cm-1	—	Text Exact Reported	3383 · Proton conductivity properties · Figure S5b
proton conductivity of complex 1 at 97% RH, room temperature	8.68 x 10^-3 S cm^-1 at 97% RH	0.00868 S cm-1	—	Text Exact Reported	3383 · Proton conductivity properties · Figure S5b

complex 1 crystalline powder disc with silver glue electrodes · Pellet

temperature-dependent proton conductivity at 97% RH from 328 K to 368 K

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
proton conductivity of complex 1 at 328 K and 97% RH	1.13 x 10^-2 S cm^-1 at 328 K	0.0113 S cm-1	—	Text Exact Reported	3383 · Proton conductivity properties · Figure 4
best reported proton conductivity of complex 1 at 368 K and 97% RHMarked as a best value within this paper	1.75 x 10^-2 S cm^-1 at 368 K	0.0175 S cm-1	—	Text Exact Reported	3383 · Proton conductivity properties · Figure 4
activation energy from Arrhenius fit	0.15 eV	0.15 eV	—	Text Exact Reported	3383 · Proton conductivity properties · Figure 4 inset