Other — Lanthanide-Hypophosphite Frameworks with Guanidinium Guest Showing High Proton Conductivity

6 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

complex 1 colourless crystals / polycrystalline powder · Powder

temperature-dependent chi_m T and inverse susceptibility for complex 1; polycrystalline sample embedded in vaseline

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
chi_m T of complex 1 at 2 K	7.06 cm3 K mol-1 at 2 K	7.06 cm3 K mol-1	—	Text Exact Reported	3384 · Magnetic properties · Figure 5
chi_m T of complex 1 at room temperature	7.65 cm3 K mol-1	7.65 cm3 K mol-1	—	Text Exact Reported	3384 · Magnetic properties · Figure 5
Curie constant from Curie-Weiss fit	C = 7.68 cm3 K mol-1	7.68 cm3 K mol-1	—	Text Exact Reported	3384 · Magnetic properties · Figure 5
Weiss temperature from Curie-Weiss fit	theta = -0.29 K	-0.29 K	—	Text Exact Reported	3384 · Magnetic properties · Figure 5

complex 1 colourless crystals / polycrystalline powder · Powder

M-H measured between 0 and 7 T at low temperatures

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
magnetisation of complex 1 at 7 T and 2 K	6.78 N beta at 7 T and 2 K	6.78 N beta	—	Text Exact Reported	3384 · Magnetic properties · Figure S6

complex 1 colourless crystals / polycrystalline powder · Powder

TGA trace shown in Figure S2a; text reports the complexes are stable up to 350-400 K

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
reported lower end of thermal stability range for complex 1	stable up to 350-400 K	350 K	range upper end 400 K	Text Range	3382 · Background and Originality Content · Figure S2

complex 2 imidazolium Gd hypophosphite crystals · Powder

TGA trace shown in Figure S2b; text reports the complexes are stable up to 350-400 K

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
reported lower end of thermal stability range for complex 2	stable up to 350-400 K	350 K	range upper end 400 K	Text Range	3382 · Background and Originality Content · Figure S2

complex 3 pyrazole-derived Gd hypophosphite crystals · Powder

TGA trace shown in Figure S2c; text reports the complexes are stable up to 350-400 K

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
reported lower end of thermal stability range for complex 3	stable up to 350-400 K	350 K	range upper end 400 K	Text Range	3382 · Background and Originality Content · Figure S2

complex 4 triazolium Gd hypophosphite crystals · Powder

TGA trace shown in Figure S2d; text reports the complexes are stable up to 350-400 K

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
reported lower end of thermal stability range for complex 4	stable up to 350-400 K	350 K	range upper end 400 K	Text Range	3382 · Background and Originality Content · Figure S2