Complete recipeSource: Main
Route 1: Other
3 · Reference 8
Metal precursorsAg2O (116 mg, 0.5 mmol)
Linker precursorsbenzene-1,3,5-tricarboxylate/benzene-1,3,5-tricarboxylic acid (210 mg, 1 mmol); 2-aminopyrazine (94 mg, 1 mmol)
SolventsCH3OH-H2O mixed solvent, 10 ml, v/v 1/1
AdditivesAqueous NH3 solution (25%) dropped in to give a clear solution
AtmosphereDarkness during slow evaporation; atmosphere otherwise not specified
Temperatureroom temperature
Time0.5 h stirring, then several weeks slow evaporation
Work-upCrystals isolated by deionised water and dried in air.
ActivationNo activation reported.
Scalability contextYield ca. 65% based on Ag; small-crystal slow-evaporation procedure with no scale-up discussion.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Ag2O | 116 mg, 0.5 mmol | 3 · Reference 8 |
| Linker | benzene-1,3,5-tricarboxylate | 210 mg, 1 mmol | 3 · Reference 8 |
| Linker | 2-aminopyrazine | 94 mg, 1 mmol | 3 · Reference 8 |
| Solvent | CH3OH-H2O | 10 ml, v/v 1/1 | 3 · Reference 8 |
| Base | aqueous NH3 solution | dropped into the mixture until clear · 25% | 3 · Reference 8 |