Complete recipeSource: Main
Route 1: Hydrothermal
2 · 2.2 Synthetic procedures · Table 1
Metal precursorsCu(OAc)2.H2O and/or Co(OAc)2.4H2O according to Table 1
Linker precursorsHHTP
Solvents5 mL ultrapure water for metal salt; 5 mL DMF for HHTP/NH4OH
Additives0.12 mL aqueous ammonia (NH4OH, 28% NH3)
Atmospherenot specified
Temperature85
Time2
Substrate orientationnot applicable
Oxidant / reductantnone specified
Work-upnatural cooling; washed with deionized water and acetone 6 times respectively; vacuum dried at 60 C overnight
Activationvacuum oven drying at 60 C overnight
Scalability context20 mL beaker batch; no scale-up data reported.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Cupric acetate monohydrate (Cu(OAc)2.H2O) | 0 mg | 2 · 2.2 Synthetic procedures · Table 1 |
| Metal Source | Cobalt acetate tetrahydrate (Co(OAc)2.4H2O) | 100.0 mg | 2 · 2.2 Synthetic procedures · Table 1 |
| Linker | 2,3,6,7,10,11-hexahydroxytriphenylene hydrate (HHTP) | 65 mg | 2 · 2.2 Synthetic procedures · Table 1 |
| Solvent | ultrapure water | 5 mL | 2 · 2.2 Synthetic procedures · Table 1 |
| Solvent | N,N-dimethylformamide (DMF) | 5 mL | 2 · 2.2 Synthetic procedures · Table 1 |
| Base | aqueous ammonia | 0.12 mL · 28% NH3 | 2 · 2.2 Synthetic procedures · Table 1 |