Electrochemistry Application — Synthesis and characterization of a novel kind soluble, conjugated, and fluorescent chelate polymer containing fluorene ring in the backbone: Optical, electrical, and electrochemical properties

Measurement evidence

Electrochemistry Application

Synthesis and characterization of a novel kind soluble, conjugated, and fluorescent chelate polymer containing fluorene ring in the backbone: Optical, electrical, and electrochemical properties · Yildirim M., Kaya I. · Synthetic Metals · 2011 · 13-22

1 measurement group · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry using CHI 660 C Electrochemical Analyzer

poly(3,4-HBA-Cr-FDA) bulk chelate polymer · Powder

DMSO/acetonitrile 1/4 v/v; 20 mV/s; argon-filled dry box; Pt working/counter electrodes, Ag wire reference, Fc/Fc+ calibration.

Temperature: room temperature
Atmosphere: argon dry box
Geometry: three-electrode electrochemical cell
Context: pristine polymer and model compounds
Measurement source: 16,19 · 2.4. Optical and electrochemical properties; 3.3. Optical and electrochemical properties · Fig. 5; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MC-1 oxidation peak potential	1970 mV	1.97 V	—	Text Exact Reported	19 · 3.3. Optical and electrochemical properties · Fig. 5
MC-1 HOMO energy	-6.36 eV	—	—	Table Exact Reported	19 · 3.3. Optical and electrochemical properties · Table 2
MC-2 oxidation peak potential	1510 mV	1.51 V	—	Text Exact Reported	19 · 3.3. Optical and electrochemical properties · Fig. 5
MC-2 HOMO energy	-5.90 eV	—	—	Table Exact Reported	19 · 3.3. Optical and electrochemical properties · Table 2
polymer oxidation peak potential	1370 mV	1.37 V	—	Text Exact Reported	19 · 3.3. Optical and electrochemical properties · Fig. 5
polymer reduction peak potential	-1040 mV	-1.04 V	—	Text Exact Reported	19 · 3.3. Optical and electrochemical properties · Fig. 5
polymer electrochemical band gap	2.41 eV	—	—	Table Exact Reported	19 · 3.3. Optical and electrochemical properties · Table 2
polymer HOMO energy	-5.76 eV	—	—	Table Exact Reported	19 · 3.3. Optical and electrochemical properties · Table 2
polymer LUMO energy	-3.35 eV	—	—	Table Exact Reported	19 · 3.3. Optical and electrochemical properties · Table 2