Other — Topochemical conversion of a dense metal-organic framework from a crystalline insulator to an amorphous semiconductor

Measurement evidence

Other

Topochemical conversion of a dense metal-organic framework from a crystalline insulator to an amorphous semiconductor · Tominaka S., Hamoudi H., Suga T. et al. · Chemical Science · 2015 · 1465-1473

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Elemental analysis (CHN/Cl)

Compound 3 vacuum-dried black monolith · Unknown

Chemical compositions reported for compounds 1, 2, 3, and a 5-day-treated sample.

Context
pristine framework and post-synthetically converted products
Measurement source
2 · Experimental - Synthesis
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Compound 1 elemental compositionFound/calcd wt% for C3H3N3S3CuCl: C 13.33/13.04, H 1.00/1.09, N 15.26/15.21, Cl 12.96/12.83Text
Exact Reported
2 · Experimental - Synthesis
Compound 2 assigned composition(H3O)0.7(NH4)0.5[Cu1.8(ttc)]; found C 10.76, H 1.23, N 14.70, Cl 0.00 wt%Text
Exact Reported
3 · Appearance & composition
5-day-treated sample compositionFound C 12.24, H 0.50, N 14.39, Cl 0.00 wt%; C:H:N = 1.00:0.49:1.01Text
Exact Reported
2 · Experimental - Synthesis
Compound 3 assigned compositionCu1.8(ttcH1.2), i.e. CuI1.8(ttc)0.6(ttcH3)0.4; found C 12.33, H 0.45, N 14.28, Cl 0.00 wt%Text
Exact Reported
3 · Appearance & composition

Simultaneous DSC-TGA

Compound 3 vacuum-dried black monolith · Unknown

TA Instruments Q600 SDT, room temperature to 600 deg C, air or N2 flow 100 mL min-1, heating rate 5 deg C min-1.

Temperature
room temperature to 873
Atmosphere
air or nitrogen
Context
compound 3 compared with compounds 1 and 2
Measurement source
S4 · Thermogravimetric analysis · Figure S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource