Synthesis · Tailoring Li-ion Storage and Transport in Two-Dimensional Conjugated Metal-Organic Frameworks via Precise Nitrogen Incorporation

7 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

13 · Synthesis of Cu-N2-OHBA · Scheme S3

Show 6 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	N2-OHBA	15.2 mg, 0.03 mmol	13 · Synthesis of Cu-N2-OHBA · Scheme S3
Solvent	degassed N,N-dimethylformamide (DMF)	1 mL	13 · Synthesis of Cu-N2-OHBA · Scheme S3
Metal Source	Cu(NO3)2.3H2O	18.2 mg, 0.075 mmol	13 · Synthesis of Cu-N2-OHBA · Scheme S3
Solvent	H2O	2 mL	13 · Synthesis of Cu-N2-OHBA · Scheme S3
Solvent	DI H2O	150 mL x 2	13 · Synthesis of Cu-N2-OHBA · Scheme S3
Solvent	acetone	15 mL x 2	13 · Synthesis of Cu-N2-OHBA · Scheme S3

Complete recipeSource: SI

42 · 6.1. Electrode preparation

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	carbon paper HCP020P	1.5 x 1 cm strips	42 · 6.1. Electrode preparation
Other	Cu-N4-OHBA	24 mg	42 · 6.1. Electrode preparation
Additive	Super P	3 mg	42 · 6.1. Electrode preparation
Other	PTFE aqueous suspension	3 mg · 30 wt%	42 · 6.1. Electrode preparation
Solvent	ethanol	1 mL	42 · 6.1. Electrode preparation

Complete recipeSource: Both

13 · Synthesis of Cu-N4-OHBA · Scheme S4

Show 6 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	N4-OHBA	18.3 mg, 0.03 mmol	13 · Synthesis of Cu-N4-OHBA · Scheme S4
Solvent	degassed N,N-dimethylformamide (DMF)	2 mL	13 · Synthesis of Cu-N4-OHBA · Scheme S4
Metal Source	Cu(NO3)2.3H2O	18.2 mg, 0.075 mmol	13 · Synthesis of Cu-N4-OHBA · Scheme S4
Solvent	H2O	1 mL	13 · Synthesis of Cu-N4-OHBA · Scheme S4
Solvent	DI H2O	150 mL x 2	13 · Synthesis of Cu-N4-OHBA · Scheme S4
Solvent	acetone	15 mL x 2	13 · Synthesis of Cu-N4-OHBA · Scheme S4

Complete recipeSource: SI

42 · 6.1. Electrode preparation

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	carbon paper HCP020P	1.5 x 1 cm strips	42 · 6.1. Electrode preparation
Other	Cu-N2-OHBA	24 mg	42 · 6.1. Electrode preparation
Additive	Super P	3 mg	42 · 6.1. Electrode preparation
Other	PTFE aqueous suspension	3 mg · 30 wt%	42 · 6.1. Electrode preparation
Solvent	ethanol	1 mL	42 · 6.1. Electrode preparation

Complete recipeSource: SI

14 · Activation of Cu-Nx-OHBA

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Cu-Nx-OHBA powder	not specified	14 · Activation of Cu-Nx-OHBA
Solvent	acetone	5 mL portions	14 · Activation of Cu-Nx-OHBA

Complete recipeSource: SI

6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1

Show 11 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	perchloropyrazine 1	1.0 g, 4.59 mmol	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Other	(3,4-dimethoxyphenyl)boronic acid 2	5.3 g, 29.0 mmol	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Additive	Pd(PPh3)4	580 mg, 0.5 mmol	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Base	K2CO3 aqueous solution	27 mL · 2.0 M	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Solvent	deoxygenated dimethoxyethane (DME)	60 mL	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Oxidant	FeCl3	2.6 g	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Solvent	nitromethane	20 mL	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Solvent	anhydrous chloroform	60 mL	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Other	BBr3 in dichloromethane	60.0 mL · 1.0 M	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Other	degassed anhydrous MeOH	50 mL	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1
Solvent	degassed dichloromethane	100 mL x 3	6 · 2.2. Synthesis of N2-OHBA ligand · Scheme S1

Partial recipeSource: SI

10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2

Show 9 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	compound 5	726 mg, 1.0 mmol	10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2
Oxidant	FeCl3	2.0 g	10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2
Solvent	nitromethane	20 mL	10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2
Solvent	anhydrous chloroform	60 mL	10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2
Solvent	MeOH	100 mL x 3	10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2
Other	compound 6	1.08 g, 1.5 mmol	10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2
Other	BBr3 in DCM	60 mL · 1.0 M	10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2
Solvent	anhydrous dichloromethane	40 mL	10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2
Other	degassed MeOH	50 mL	10 · 2.3. Synthesis of N4-OHBA ligand · Scheme S2