Primary studyCore evidenceTransport Physics

Reconstruction of Co/Ni metal-organic-framework based electrode materials with excellent conductivity and integral stability via extended hydrothermal treatment toward improved performance of supercapacitors

Ji Y., Ren F., Tan S. et al. · Journal of Electroanalytical Chemistry · 2023 · 117265

3materials
6samples
5synthesis routes
17measurements
59results
5claims and caveats

Evidence map

Open a family to keep every result attached to its sample, method and conditions.

Author interpretations and caveats

Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.

Application RelevanceSupport assessment: High

The reconstructed Co/Ni-MOF@CC-12 electrode gives high single-electrode capacity and an ASC with high energy density and cycle retention.

Caveat: Device performance is application-specific and measured with an active-carbon negative electrode.

6 · 5 Conclusion · Linked to 4 structured results

CaveatSupport assessment: High

The office-text SI extraction is incomplete, but the rendered SI surrogate supplies the SI figures and Table S1-S3 bodies used for this extraction.

Caveat: Use research_0767_si_rendered_0b7c152bed for SI table-body provenance rather than the office text layer.

4 · Supporting information · Table S1-S3

Structure Property LinkSupport assessment: High

The 12 h hydrothermal sample is the optimum: 6 h is poorly crystallised while 18 h suffers serious aggregation.

Caveat: Morphology comparison is qualitative from SEM and text.

6 · 4 Results and discussion · Fig. 1; Fig. 4 · Linked to 3 structured results

Structure Property LinkSupport assessment: High

Extended hydrothermal treatment partially reconstructs Co/Ni-MOF into graphitic carbon and NiCo2O4, improving conductivity and stability.

Caveat: EIS conductivity evidence is qualitative in the main text; no numeric conductivity or resistance value is printed.

6 · 5 Conclusion · Linked to 4 structured results

Transport MechanismSupport assessment: Medium

MOF materials tightly anchored on conductive carbon fibre reduce contact resistance and accelerate electron transfer.

Caveat: Mechanistic statement is supported by EIS trend and device schematic, but not by direct conductivity measurements.

6 · 4 Results and discussion · Fig. 5b · Linked to 1 structured result

Material identities

Names and aliases are kept exactly within the paper’s own identity model.

MaterialCompositionStructure contextSource
Activated carbon clothCCunknown · PristineNitric-acid-treated conductive carbon cloth support.2 · 2.1 The activation of carbon cloth
Co/Ni-MOF@CC-12//AC asymmetric supercapacitorCo/Ni-MOF@CC-12 positive electrode // activated carbon negative electrode in 2 M KOHCo and Ni in positive electrode · isophthalic acid in positive electrodeunknown · CompositeAssembled asymmetric supercapacitor device.2 · 2.3 The assembling of asymmetric supercapacitor (ASC)
Co/Ni-MOF anchored on activated carbon clothCo/Ni-MOF@CC; partially reconstructed to graphitic carbon and NiCo2O4 after extended hydrothermal treatmentCo and Ni · isophthalic acidunknown · CompositeBimetal Co/Ni metal-organic framework nanoneedle arrays on carbon cloth; 12 h and 18 h samples show graphitic carbon and NiCo2O4 diffraction features.1 · Abstract

Sample register

Sample form, processing state and composition status define the context for measurements.

Show 6 sample records
SampleForm and roleProcessing and geometrySource
Co/Ni-MOF@CC-12//AC ASCresearch_0767__mat__mat_asc_deviceElectrode · Composite Sample · Compositeassembled two-electrode asymmetric supercapacitorcell device2 · 2.3 The assembling of asymmetric supercapacitor (ASC)
CCresearch_0767__mat__mat_activated_ccElectrode · Pristine Control · Pristine FrameworkHNO3 hydrothermally activated and vacuum driedcarbon cloth2 · 2.1 The activation of carbon cloth
Co/Ni-MOF@CC-12research_0767__mat__mat_coni_mof_ccElectrode · Target Sample · Composite12 h hydrothermal growth; optimised reconstructed sample with graphitic carbon/NiCo2O4 featuresactivated carbon cloth2 · 2.2 The synthesis of Co/Ni-MOF anchored on carbon cloth
Co/Ni-MOF@CC-18research_0767__mat__mat_coni_mof_ccElectrode · Pristine Control · Composite18 h hydrothermal growth; higher crystallinity but serious aggregationactivated carbon cloth2 · 2.2 The synthesis of Co/Ni-MOF anchored on carbon cloth
Co/Ni-MOF@CC-6research_0767__mat__mat_coni_mof_ccElectrode · Pristine Control · Composite6 h hydrothermal growth; low crystallinity/amorphous productactivated carbon cloth2 · 2.2 The synthesis of Co/Ni-MOF anchored on carbon cloth
UCCresearch_0767__mat__mat_activated_ccElectrode · Pristine Control · Pristine Frameworkunprocessed carbon cloth before nitric acid activationcarbon cloth3 · 4 Results and discussion · Fig. S1