Electrochemistry Application — Reconstruction of Co/Ni metal-organic-framework based electrode materials with excellent conductivity and integral stability via extended hydrothermal treatment toward improved performance of supercapacitors

Measurement evidence

Electrochemistry Application

Reconstruction of Co/Ni metal-organic-framework based electrode materials with excellent conductivity and integral stability via extended hydrothermal treatment toward improved performance of supercapacitors · Ji Y., Ren F., Tan S. et al. · Journal of Electroanalytical Chemistry · 2023 · 117265

7 measurement groups · 27 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

cyclic voltammetry of asymmetric supercapacitor

Co/Ni-MOF@CC-12//AC ASC · Electrode

Two-electrode ASC on LAND CT2001A; voltage windows up to 1.7 V at 5 mV s-1; scan rates 5-50 mV s-1 at selected 0-1.6 V window.

Geometry
two-electrode asymmetric supercapacitor
Context
application device
Measurement source
6 · 4 Results and discussion · Fig. 5c,d
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Selected ASC potential windowMarked as a best value within this paper0-1.6 VText
Exact Reported
6 · 4 Results and discussion · Fig. 5c

cyclic voltammetry (CHI 660E, three-electrode)

Co/Ni-MOF@CC-12 · Electrode

Working electrode: as-obtained sample; counter: Pt wire; reference: Ag/AgCl; electrolyte: 2 M KOH; potential range -0.2 to 0.6 V; scan rates 5-20 mV s-1.

Geometry
three-electrode cell
Context
Co/Ni-MOF@CC electrode series
Measurement source
6 · 4 Results and discussion · Fig. 4a,c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Largest CV area among electrode samplesMarked as a best value within this paperCo/Ni-MOF@CC-12 delivered the largest CV areaText
Qualitative
6 · 4 Results and discussion · Fig. 4a
Single-electrode CV redox peakspair of well-defined redox peaks for all samplesText
Qualitative
4 · 4 Results and discussion · Fig. 4a

cycling stability of asymmetric supercapacitor

Co/Ni-MOF@CC-12//AC ASC · Electrode

ASC cycling at 5 A g-1 for 5000 charge-discharge cycles.

Geometry
two-electrode asymmetric supercapacitor
Context
application device
Measurement source
6 · 4 Results and discussion · Fig. 5g
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ASC cycle count5000 cyclesText
Exact Reported
6 · 4 Results and discussion · Fig. 5g
ASC capacitance retention after 5000 cycles88.6 %Text
Exact Reported
6 · 4 Results and discussion · Fig. 5g

cycling stability by repeated charge-discharge

Co/Ni-MOF@CC-12 · Electrode

Single-electrode cycling at 10 A g-1 for 3000 cycles.

Geometry
three-electrode cell
Context
target composite sample
Measurement source
6 · 4 Results and discussion · Fig. 4g
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Co/Ni-MOF@CC-12 single-electrode cycle count3000 cyclesText
Exact Reported
6 · 4 Results and discussion · Fig. 4g
Co/Ni-MOF@CC-12 single-electrode capacity retention after 3000 cycles85.4 %Text
Exact Reported
6 · 4 Results and discussion · Fig. 4g

galvanostatic charge-discharge of asymmetric supercapacitor

Co/Ni-MOF@CC-12//AC ASC · Electrode

Two-electrode ASC; current densities 1, 2, 3 and 5 A g-1.

Geometry
two-electrode asymmetric supercapacitor
Context
application device
Measurement source
7 · 4 Results and discussion · Fig. 5e,f
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ASC specific capacity at 1 A g-1Marked as a best value within this paper358.1 C g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 5f
ASC specific capacity at 2 A g-1330.1 C g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 5f
ASC specific capacity at 3 A g-1324 C g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 5f
ASC specific capacity at 5 A g-1320 C g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 5f
ASC coulombic efficiency at 1 A g-180.8 %Text
Exact Reported
6 · 4 Results and discussion · Fig. 5f
ASC coulombic efficiency at 2 A g-195.3 %Text
Exact Reported
6 · 4 Results and discussion · Fig. 5f
ASC coulombic efficiency at 3 A g-194.7 %Text
Exact Reported
6 · 4 Results and discussion · Fig. 5f
ASC coulombic efficiency at 5 A g-1Marked as a best value within this paper100 %Text
Exact Reported
6 · 4 Results and discussion · Fig. 5f

galvanostatic charge-discharge (CHI 660E, three-electrode)

Co/Ni-MOF@CC-12 · Electrode

2 M KOH electrolyte; current density range 1-10 A g-1; specific capacity calculated from GCD curves.

Geometry
three-electrode cell
Context
Co/Ni-MOF@CC electrode series
Measurement source
6 · 4 Results and discussion · Fig. 4b,d,e
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Co/Ni-MOF@CC-12 specific capacity at 10 A g-1approximately 390 C g-1 from Fig. 4evisual estimateFigure Axis
Approximate
5 · Figure 4 · Fig. 4e
Co/Ni-MOF@CC-12 specific capacity at 1 A g-1Marked as a best value within this paper680.6 C g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 4e
Co/Ni-MOF@CC-12 specific capacitance at 1 A g-1Marked as a best value within this paper1701.5 F g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 4e
Co/Ni-MOF@CC-12 specific capacity at 2 A g-1approximately 560 C g-1 from Fig. 4evisual estimateFigure Axis
Approximate
5 · Figure 4 · Fig. 4e
Co/Ni-MOF@CC-12 specific capacity at 5 A g-1approximately 490 C g-1 from Fig. 4evisual estimateFigure Axis
Approximate
5 · Figure 4 · Fig. 4e
Co/Ni-MOF@CC-18 specific capacity at 1 A g-1257.8 C g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 4e
Co/Ni-MOF@CC-18 specific capacitance at 1 A g-1644.5 F g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 4e
Co/Ni-MOF@CC-6 specific capacity at 1 A g-1403.9 C g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 4e
Co/Ni-MOF@CC-6 specific capacitance at 1 A g-11009.8 F g-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 4e

Ragone energy/power density analysis

Co/Ni-MOF@CC-12//AC ASC · Electrode

Energy density and power density calculated from ASC GCD curves.

Geometry
two-electrode asymmetric supercapacitor
Context
application device
Measurement source
6 · 4 Results and discussion · Fig. 5h
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Maximum ASC energy densityMarked as a best value within this paper79.6 Wh kg-1 at 0.8 kW kg-1Text
Exact Reported
6 · 5 Conclusion · Fig. 5h
Maximum ASC power densityMarked as a best value within this paper4.0 kW kg-1Text
Exact Reported
6 · 4 Results and discussion · Fig. 5h
ASC power density at maximum reported energy density0.8 kW kg-1Text
Exact Reported
6 · 5 Conclusion · Fig. 5h