Diffraction Structure — Metal-Organic Framework Photoconductivity via Time-Resolved Terahertz Spectroscopy

Measurement evidence

Diffraction Structure

Metal-Organic Framework Photoconductivity via Time-Resolved Terahertz Spectroscopy · Pattengale B., Neu J., Ostresh S. et al. · Journal of the American Chemical Society · 2019 · 9793-9797

3 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

pXRD and SEM side-view imaging

Zn2TTFTB thin film on FTO · Thin Film

Zn2TTFTB thin film on FTO checked for crystallinity and thickness.

Geometry
FTO-coated glass substrate
Context
pristine framework film control
Measurement source
S9 · Supplementary Figures · Figure S8b-c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Thin-film crystallinitypXRD pattern confirmed correct crystallinity of Zn2TTFTB thin film on FTO.Caption
Qualitative
S9 · Supplementary Figures · Figure S8b
Zn2TTFTB film thickness on FTO10 umCaption
Exact Reported
S9 · Supplementary Figures · Figure S8c

Post-TRTS pXRD

As-prepared Zn2TTFTB tape-cell sample · Powder

Powder X-ray diffraction after TRTS beam exposure.

Geometry
Tape-cell sample after TRTS
Context
as-prepared pristine Zn2TTFTB powder in tape cell after measurement
Measurement source
S10 · Supplementary Figures · Figure S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Phase stability after TRTSPost-TRTS pXRD confirmed phase stability and retained crystallinity after beam exposure.Caption
Qualitative
S10 · Supplementary Figures · Figure S11

Powder X-ray diffraction (pXRD), Rigaku SmartLab; calculated reference from Mercury/CCDC

As-synthesised Zn2TTFTB powder · Powder

As-synthesised Zn2TTFTB compared with calculated single-crystal pattern (CSD 913459).

Context
pristine framework powder
Measurement source
p002 / 9794 · main text · Figure 1a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Powder phase puritypXRD confirmed phase-purity of crystalline Zn2TTFTB and matched calculated single-crystal reference.Text
Qualitative
p002 / 9794 · main text · Figure 1a