Synthesis · Metal-Organic Framework Photoconductivity via Time-Resolved Terahertz Spectroscopy

4 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

Route 1: Solvothermal

S2 · Synthesis and Characterization of Zn2TTFTB

Metal precursors159.5 mg Zn(NO3)2.6H2O

Linker precursors100 mg H4TTFTB

SolventsDimethylformamide and ethanol

AtmosphereEvacuated and N2-filled three times on a Schlenk line

Temperature75

Time48

Work-upDark precipitate collected by vacuum filtration and washed three times with dimethylformamide followed by ethanol.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	H4TTFTB	100 mg	S2 · Synthesis and Characterization of Zn2TTFTB
Solvent	dimethylformamide	12 mL in ligand solution; 8 mL in metal solution	S2 · Synthesis and Characterization of Zn2TTFTB
Solvent	ethanol	4 mL added to ligand solution; 8 mL in metal solution	S2 · Synthesis and Characterization of Zn2TTFTB
Metal Source	Zn(NO3)2.6H2O	159.5 mg	S2 · Synthesis and Characterization of Zn2TTFTB

Partial recipeSource: Both

Route 2: Other

p002 / 9794 · main text · Figures S4-S5

Work-upAs-prepared tape cell pressed with 11 kbar hydraulic pressure.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	As-prepared Zn2TTFTB tape cell	Not specified	p002 / 9794 · main text · Figures S4-S5

Vague recipeSource: Both

Route 3: Other

S8 · Supplementary Figures · Figure S6

AdditivesPTFE matrix

Work-upZn2TTFTB/PTFE pellet pressed at 11 kbar.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Zn2TTFTB	Not specified	S8 · Supplementary Figures · Figure S6
Additive	PTFE	Not specified	S8 · Supplementary Figures · Figure S6

Complete recipeSource: SI

Route 4: Other

S2 · Tape Cell Preparation

SolventsIsopropanol used to wipe outside of cell

AdditivesAcrylic tape and paper business card

AtmosphereAmbient sample preparation

Work-upMOF powder packed into 7 mm punched hole, lightly scraped, repeated three times, sealed with second acrylic tape layer, trimmed and wiped clean.

Scalability contextDesigned to study delicate powder samples without pressing pellets or sintering.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	As-synthesised Zn2TTFTB powder	Added to fill 7 mm punched hole	S2 · Tape Cell Preparation
Other	paper business card	0.35 +/- 0.01 mm thickness; 7 mm punched hole	S2 · Tape Cell Preparation
Other	Intertape Polymer Group model 291 acrylic tape	2.5 mil = 63.5 um thickness; two pieces	S2 · Tape Cell Preparation
Solvent	isopropanol	Used to wipe clean outside of cell	S2 · Tape Cell Preparation