cMOF Evidence Base

Synthesis evidence

One-Dimensional π-d Conjugated Conductive Metal-Organic Framework with Dual Redox-Active Sites for High-Capacity and Durable Cathodes for Aqueous Zinc Batteries

Sang Z., Liu J., Zhang X. et al. · ACS Nano · 2023 · 3077-3087

4 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

3084 · Electrochemical Measurement

AdditivesKetjen Black (ECP-600JD); PTFE 60 wt% dispersion
Atmospherecoin-cell assembly atmosphere not reported
Work-upMixed into cathode nanosheet; assembled in CR2032 coin cells with zinc foil anode.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherCu-BTA-H powder7 parts by weight3084 · Electrochemical Measurement
AdditiveKetjen Black (ECP-600JD)2 parts by weight3084 · Electrochemical Measurement
Additivepolytetrafluoroethylene (PTFE) dispersion1 part by weight · 60 wt%3084 · Electrochemical Measurement
ElectrolyteZnSO4 aqueous solution2.5 M3084 · Electrochemical Measurement
Complete recipeSource: Main

Route 2: Hydrothermal

3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H

Metal precursorsCuCl2
Linker precursorsBTA.4HCl
Solventsdeionised water; acetone wash
Additivesconcentrated aqueous ammonia solution (approximately 14 M)
Atmospheresealed bottles; gas atmosphere not specified
Temperature60
Time12
Work-upPowders washed three times with deionised water and acetone.
ActivationDried at 60 deg C under vacuum.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCuCl226.8 mg (0.2 mmol)3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
LinkerBTA.4HCl56.8 mg (0.2 mmol)3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Solventdeionized water10 mL for CuCl2 solution; 10 mL for BTA.4HCl solution3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Baseconcentrated aqueous ammonia solution0.5 mL · approximately 14 M3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Solventacetonewash solvent3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Complete recipeSource: Main

Route 3: Other

3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H

Metal precursorsCuCl2
Linker precursorsBTA.4HCl
Solventsdeionised water; acetone wash
Additivesconcentrated aqueous ammonia solution (approximately 14 M)
Atmosphereambient atmosphere not otherwise specified
Temperatureroom temperature
Timeapproximately 3.33
Work-upPowder washed three times with deionised water and acetone.
ActivationDried at 60 deg C under vacuum.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCuCl20.2 mmol3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
LinkerBTA.4HCl0.2 mmol3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Solventdeionized water10 mL for linker solution; 10 mL for metal solution3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Baseconcentrated aqueous ammonia solution0.5 mL · approximately 14 M3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Solventacetonewash solvent3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Complete recipeSource: Main

Route 4: Other

3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H

Metal precursorsNiCl2.6H2O
Linker precursorsBTA.4HCl
Solventsdeionised water; acetone wash
Additivesconcentrated aqueous ammonia solution (approximately 14 M)
Atmosphereambient atmosphere not otherwise specified
Temperatureroom temperature
Timeapproximately 3.33
Work-upPowder washed three times with deionised water and acetone.
ActivationDried at 60 deg C under vacuum.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceNiCl2.6H2O0.2 mmol3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
LinkerBTA.4HCl0.2 mmol3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Solventdeionized water10 mL for solution A; 10 mL for metal solution3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Baseconcentrated aqueous ammonia solution0.5 mL · approximately 14 M3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H
Solventacetonewash solvent3084 · Experimental Section - Preparation of Cu-BTA-H, Cu-BTA-L, and Ni-BTA-H