Porosity — Overcoming Diffusion Limitation of Faradaic Processes: Property-Performance Relationships of 2D Conductive Metal-Organic Framework Cu3(HHTP)2 for Reversible Lithium-Ion Storage

Measurement evidence

Porosity

Overcoming Diffusion Limitation of Faradaic Processes: Property-Performance Relationships of 2D Conductive Metal-Organic Framework Cu3(HHTP)2 for Reversible Lithium-Ion Storage · Wrogemann J.M., Luther M.J., Barmann P. et al. · Angewandte Chemie - International Edition · 2023 · e202303111

2 measurement groups · 44 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 physisorption, BET and t-plot

Flake-like Cu3(HHTP)2 powder activated at 60 C · Powder

Micromeritics 3Flex; N2 at 77 K; degassed under reduced pressure for 20 h at RT-120 C, with 60 C used for electrode-relevant activation.

Temperature
77
Atmosphere
nitrogen adsorptive
Geometry
powder
Context
pristine powder
Measurement source
p004 · Results and Discussion · Figure 1e,f; Figure S7-S9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Flake-like total BET surface area at 100 C degassing555 m2 g-1Calculated From Reported
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like total BET surface area at 120 C degassing541 m2 g-1Calculated From Reported
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like BET surface area after 60 C degassing557 m2 g-1Text
Rounded Reported
p004 · Results and Discussion · Figure 1f
Flake-like total BET surface area at 80 C degassingMarked as a best value within this paper575 m2 g-1Calculated From Reported
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Maximum flake-like BET surface areaMarked as a best value within this paper575 m2 g-1 after degassing at 80 CText
Rounded Reported
p004 · Results and Discussion · Figure S9
Flake-like total BET surface area at r.t. degassing409 m2 g-1Calculated From Reported
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like external surface area at 100 C degassing126 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like external surface area at 120 C degassing127 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like external surface area at 60 C133 m2 g-1Figure Axis
Rounded Reported
p003 · Results and Discussion · Figure 1f
Flake-like external surface area at 80 C degassing128 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like external surface area at r.t. degassing111 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like microporous surface area at 100 C degassing429 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like microporous surface area at 120 C degassing414 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like microporous surface area at 60 C424 m2 g-1Figure Axis
Rounded Reported
p003 · Results and Discussion · Figure 1f
Flake-like microporous surface area at 80 C degassing447 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like microporous surface area at r.t. degassing298 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like microporous surface-area fraction at 100 C degassing77.3% from 429/555Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like microporous surface-area fraction at 120 C degassing76.5% from 414/541Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like microporous surface-area fraction at 60 C degassing76.1% from 424/557Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like microporous surface-area fraction at 80 C degassing77.7% from 447/575Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like microporous surface-area fraction at r.t. degassing72.9% from 298/409Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Flake-like pore diameter from t-plot model1.62 nmText
Rounded Reported
S-17 · 2.5

N2 physisorption, BET and t-plot

Rod-like Cu3(HHTP)2 powder activated at 60 C · Powder

Micromeritics 3Flex; N2 at 77 K; degassed under reduced pressure for 20 h at RT-120 C, with 60 C used for electrode-relevant activation.

Temperature
77
Atmosphere
nitrogen adsorptive
Geometry
powder
Context
pristine powder
Measurement source
p004 · Results and Discussion · Figure 1e,f; Figure S7-S9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Rod-like total BET surface area at 100 C degassingMarked as a best value within this paper245 m2 g-1Calculated From Reported
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like total BET surface area at 120 C degassing228 m2 g-1Calculated From Reported
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like BET surface area after 60 C degassing157 m2 g-1Text
Rounded Reported
p004 · Results and Discussion · Figure 1f
Rod-like total BET surface area at 80 C degassing208 m2 g-1Calculated From Reported
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Maximum rod-like BET surface areaMarked as a best value within this paper245 m2 g-1 after degassing at 100 CText
Rounded Reported
p004 · Results and Discussion · Figure S9
Rod-like total BET surface area at r.t. degassing97 m2 g-1Calculated From Reported
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like external surface area at 100 C degassing72 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like external surface area at 120 C degassing68 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like external surface area at 60 C71 m2 g-1Figure Axis
Rounded Reported
p003 · Results and Discussion · Figure 1f
Rod-like external surface area at 80 C degassing66 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like external surface area at r.t. degassing53 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like microporous surface area at 100 C degassing173 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like microporous surface area at 120 C degassing160 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like microporous surface area at 60 C86 m2 g-1Figure Axis
Rounded Reported
p003 · Results and Discussion · Figure 1f
Rod-like microporous surface area at 80 C degassing142 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like microporous surface area at r.t. degassing44 m2 g-1Figure Axis
Rounded Reported
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like microporous surface-area fraction at 100 C degassing70.6% from 173/245Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like microporous surface-area fraction at 120 C degassing70.2% from 160/228Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like microporous surface-area fraction at 60 C degassing54.8% from 86/157Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like microporous surface-area fraction at 80 C degassing68.3% from 142/208Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like microporous surface-area fraction at r.t. degassing45.4% from 44/97Calculated From Reported
Approximate
S-18 · 2.5 Material characterization via physisorption experiments · Figure S9
Rod-like pore diameter from t-plot model1.66 nmText
Rounded Reported
S-17 · 2.5