Synthesis · Elucidating d-π conjugated two-dimensional 2,3,6,7,10,11-hexahydroxytriphenylene based conductive metal-organic framework for hybrid supercapacitors

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

5 · 3.3. Electrochemical evaluation of asymmetric device · Equation 1; Figure 5

Additives3 M KOH electrolyte

Atmospherenot specified

Substrate orientationNi3(HHTP)2 positive electrode and activated carbon negative electrode on nickel foam

Work-upcharge balanced before deposition/assembly using capacitance and potential-window equation

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Ni3(HHTP)2 positive electrode	charge balanced; exact device mass not stated	5 · 3.3. Electrochemical evaluation of asymmetric device · Equation 1; Figure 5
Other	activated carbon negative electrode	charge balanced; exact device mass not stated	5 · 3.3. Electrochemical evaluation of asymmetric device · Equation 1; Figure 5
Electrolyte	KOH	3 M	5 · 3.3. Electrochemical evaluation of asymmetric device · Equation 1; Figure 5

Partial recipeSource: Main

2 · 2.2. Synthesis of Ni3(HHTP)2

Metal precursors10.5 mg Ni(OAc)2.4H2O

Linker precursors7.5 mg HHTP

Solvents4 ml deionized water

Atmospherenot specified

Temperature85

Time12

Work-upnatural cooling to room temperature; filtered; washed with DI water and acetone; dried in air

Activationnot specified

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(OAc)2.4H2O	10.5 mg	2 · 2.2. Synthesis of Ni3(HHTP)2
Linker	HHTP	7.5 mg	2 · 2.2. Synthesis of Ni3(HHTP)2
Solvent	deionized water	4 ml	2 · 2.2. Synthesis of Ni3(HHTP)2

Partial recipeSource: Main

2 · 2.3. Slurry and electrode preparation

SolventsNMP

Additivesacetylene black; binder

Atmosphereair assumed during hot-plate stirring and oven heating; not explicitly specified

Temperature70

Time9 h stirring plus 5 h oven heating

Substrate orientationnickel foam, 1 x 1 cm2

Work-upslurry deposited on nickel foam and heated in oven at 70 C for 5 h

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Ni3(HHTP)2	80 wt%	2 · 2.3. Slurry and electrode preparation
Additive	acetylene black	10 wt%	2 · 2.3. Slurry and electrode preparation
Additive	binder (PVDF listed in materials)	5 wt%	2 · 2.3. Slurry and electrode preparation
Solvent	NMP	5 wt%	2 · 2.3. Slurry and electrode preparation