Porosity — Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal-Organic Framework

Measurement evidence

Porosity

Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal-Organic Framework · Park J., Hinckley A.C., Huang Z. et al. · Journal of the American Chemical Society · 2018 · 14533-14537

2 measurement groups · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 sorption isotherm and BET surface area

Gas sorption and porosity

Cu-HHB H2O 60 C post-treated powder · Powder

Gas adsorption measured using Autosorb IQ2; post-treated Cu-HHB samples compared after water washing at 60 C and 100 C.

Atmosphere: N2 adsorption measurement
Geometry: Powder sorption sample
Context: Post-treated pristine Cu-HHB powder
Measurement source: p003 · Main text · Figure 3d; Figures S6-S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
As-synthesised Cu-HHB porosity before post-treatment	no measurable porosity	—	—	Text Qualitative	S7 · Post-treatment of Cu-HHB · Figures S6-S7
BET surface area, Cu-HHBMarked as a best value within this paper	~158 m2 g-1	—	~	Text Approximate	p003 · Main text · Figures S6-S9

N2 sorption isotherm and BET surface area

Gas sorption and porosity

Cu-THQ H2O 60 C post-treated powder · Powder

Gas adsorption measured using Autosorb IQ2; Cu-THQ pristine, H2O @ 60 C and H2O @ 100 C treatments compared.

Atmosphere: N2 adsorption measurement
Geometry: Powder sorption sample
Context: Post-treated pristine Cu-THQ powder
Measurement source: p003 · Main text · Figure 3d; Figures S15-S18

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area, Cu-THQ	~143 m2 g-1	—	~	Text Approximate	p003 · Main text · Figure 3d; Figures S15-S18