Spectroscopy — Electrically conductive Pt-MOFs for acidic oxygen reduction: Optimized performance via altering conjugated ligands

Measurement evidence

Spectroscopy

Electrically conductive Pt-MOFs for acidic oxygen reduction: Optimized performance via altering conjugated ligands · Iqbal R., Ali S., Saleem A. et al. · Chemical Engineering Journal · 2023 · 140799

1 measurement group · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

EXAFS, XANES and XPS

Pt3(C12N6O6)2 MOF black powder · Powder

Pt L3-edge XAS and Pt 4f XPS used to assign Pt-O coordination and Pt2+ state.

Geometry
powder
Context
pristine framework
Measurement source
p. 5 · 3.1 · Fig. 3c-d; Fig. S4; Fig. S19; Table S12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
EXAFS fitted Pt-O bond distance1.92 ASI Table
Exact Reported
p. 28 · EXAFS Spectrum Fitting · Table S12
EXAFS fitted Pt-O coordination number3.8SI Table
Exact Reported
p. 28 · EXAFS Spectrum Fitting · Table S12
EXAFS inner potential correction DeltaE00.8 eVSI Table
Exact Reported
p. 28 · EXAFS Spectrum Fitting · Table S12
EXAFS R factor0.0095SI Table
Exact Reported
p. 28 · EXAFS Spectrum Fitting · Table S12
EXAFS Debye-Waller factor0.0125 A^2SI Table
Exact Reported
p. 28 · EXAFS Spectrum Fitting · Table S12
FT-EXAFS main peak1.61 AText
Exact Reported
p. 4 · 3.1 · Fig. 3c
FT-EXAFS additional peak2.6 AText
Rounded Reported
p. 4 · 3.1 · Fig. 3c
Pt L3-edge XANES peak11566.8 eVText
Exact Reported
p. 5 · 3.1 · Fig. 3d
Pt 4f5/2 binding energy76.1 eVText
Exact Reported
p. 5 · 3.1 · Fig. S4
Pt 4f7/2 binding energy72.8 eVText
Exact Reported
p. 5 · 3.1 · Fig. S4