Electrochemistry Application — A conductive anionic Co-MOF cage with zeolite framework for supercapacitors

5 measurement groups · 39 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

Voltammetry

Co-MOF on Ni foam · Electrode

CHI660E workstation; three-electrode cell; 3.0 mol/L KOH; Pt counter; Hg/HgO reference; potential range 0.0-0.5 V; scan rates 5-200 mV/s.

Geometry: Ni-foam-grown Co-MOF working electrode, no conductive additives or binder
Context: pristine Co-MOF electrode control
Measurement source: main p.3 · Electrochemical tests · Fig. 4a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

Cyclic voltammetry of CTAB series

Voltammetry

Co-CTAB-6 · Electrode

CV curves at 10 mV/s for Co-MOF and Co-CTAB-1/2/4/6/8 in 3 mol/L KOH; oxidation peak currents and ratios tabulated.

Geometry: Ni foam working electrodes
Context: CTAB-modified Co-MOF series compared with pristine Co-MOF
Measurement source: main p.4 · Results and discussion · Fig. 6a, Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-CTAB-1 oxidation peak current at 0.35 V	2.85	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-1 oxidation peak current at 0.425 V	3.27	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-1 oxidation peak current ratio	1.14737	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-2 oxidation peak current at 0.35 V	3.98	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-2 oxidation peak current at 0.425 V	4.83	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-2 oxidation peak current ratio	1.21357	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-4 oxidation peak current at 0.35 VMarked as a best value within this paper	4.39	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-4 oxidation peak current at 0.425 V	5.55	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-4 oxidation peak current ratio	1.26424	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-6 oxidation peak current at 0.35 V	3.59	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-6 oxidation peak current at 0.425 VMarked as a best value within this paper	7.12	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-6 oxidation peak current ratio	1.98329	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-8 oxidation peak current at 0.35 V	2.39	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-8 oxidation peak current at 0.425 V	5.22	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-8 oxidation peak current ratioMarked as a best value within this paper	2.1841	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-MOF oxidation peak current at 0.35 V	3.54	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-MOF oxidation peak current at 0.425 V	4.73	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-MOF oxidation peak current ratio	1.33616	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
first oxidation peak potential	around 0.35 V	—	—	Text Approximate	main p.4 · Results and discussion · Fig. 6a, Table 1
second oxidation peak potential	around 0.425 V	—	—	Text Approximate	main p.4 · Results and discussion · Fig. 6a, Table 1
common reduction peak potential	nearly 0.294 V	—	—	Text Approximate	main p.4 · Results and discussion · Fig. 6a

Cycling stability / capacitance retention

Co-CTAB-6 · Electrode

Co-MOF and Co-CTAB-6 capacitance retention after 3000 cycles.

Geometry: Ni foam working electrodes
Context: Co-CTAB-6 compared with pristine Co-MOF
Measurement source: main p.5 · Results and discussion · Fig. 7b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-CTAB-6 capacitance retention after 3000 cyclesMarked as a best value within this paper	77.92% after 3000 cycles	—	—	Text Exact Reported	main p.5 · Results and discussion · Fig. 7b
Co-MOF capacitance retention after 3000 cycles	64.04% after 3000 cycles	—	—	Text Exact Reported	main p.5 · Results and discussion · Fig. 7b

Galvanostatic charge-discharge

Galvanostatic cycling

Co-MOF on Ni foam · Electrode

Three-electrode cell in 3.0 mol/L KOH; potential range 0.0-0.5 V; current densities reported from 0.5 to 20 A/g.

Geometry: Ni-foam-grown Co-MOF working electrode
Context: pristine Co-MOF electrode control
Measurement source: main p.2 · Electrochemical tests · Fig. 4b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-MOF specific capacitance at 0.5 A/gMarked as a best value within this paper	240 F/g at 0.5 A/g	—	—	Text Rounded Reported	main p.3 · Results and discussion · Fig. 4b
Co-MOF specific capacitance at 10 A/g	144 F/g at 10 A/g	—	—	Text Rounded Reported	main p.3 · Results and discussion · Fig. 4b
Co-MOF specific capacitance at 1 A/g	236.2 F/g at 1 A/g	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-MOF capacitance retention at 10 A/g versus 1 A/g	61%	—	—	Text Rounded Reported	main p.3 · Results and discussion · Fig. 4b

Galvanostatic charge-discharge/specific capacitance of CTAB series

Galvanostatic cycling

Co-CTAB-6 · Electrode

Specific capacitance at 1 A/g for Co-MOF and CTAB series from Table 1; selected rate values from main text and Fig. 7a.

Geometry: Ni foam working electrodes
Context: CTAB-modified Co-MOF series compared with pristine Co-MOF
Measurement source: main p.4 · Results and discussion · Fig. 6b, Fig. 7a, Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-CTAB-1 specific capacitance at 1 A/g	208.2 F/g	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-2 specific capacitance at 1 A/g	210.0 F/g	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-4 specific capacitance at 1 A/g	285.6 F/g	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-6 specific capacitance at 0.5 A/gMarked as a best value within this paper	360 F/g at 0.5 A/g	—	—	Text Rounded Reported	main p.5 · Results and discussion · Fig. 6b
Co-CTAB-6 specific capacitance at 10 A/g	158 F/g at 10 A/g	—	—	Text Rounded Reported	main p.5 · Results and discussion · Fig. 7a
Co-CTAB-6 specific capacitance at 1 A/gMarked as a best value within this paper	334.0 F/g	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-6 capacitance retention at 10 A/g versus 1 A/g	47%	—	—	Text Rounded Reported	main p.5 · Results and discussion · Fig. 7a
Co-CTAB-8 specific capacitance at 1 A/g	286.4 F/g	—	—	Table Exact Reported	main p.3 · Results and discussion · Table 1
Co-CTAB-6 specific capacitance at 15 A/g	approximately 125 F/g from Fig. 7a	—	visual estimate	Visual Estimate Approximate	main p.4 · Results and discussion · Fig. 7a
Co-CTAB-6 specific capacitance at 2 A/g	approximately 285 F/g from Fig. 7a	—	visual estimate	Visual Estimate Approximate	main p.4 · Results and discussion · Fig. 7a
Co-MOF specific capacitance at 15 A/g	approximately 120 F/g from Fig. 7a	—	visual estimate	Visual Estimate Approximate	main p.4 · Results and discussion · Fig. 7a
Co-MOF specific capacitance at 2 A/g	approximately 215 F/g from Fig. 7a	—	visual estimate	Visual Estimate Approximate	main p.4 · Results and discussion · Fig. 7a