cMOF Evidence Base
Electrical Transport — Mechanistic Evidence for Ligand-Centered Electrocatalytic Oxygen Reduction with the Conductive MOF Ni3(hexaiminotriphenylene)2

Measurement evidence

Electrical Transport

Mechanistic Evidence for Ligand-Centered Electrocatalytic Oxygen Reduction with the Conductive MOF Ni3(hexaiminotriphenylene)2 · Miner E.M., Gul S., Ricke N.D. et al. · ACS Catalysis · 2017 · 7726-7731

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

chemiresistive current/resistance measurement

Ni3(HITP)2 film on gold interdigitated electrode · Electrode

0.1 M KOH sparged with N2; constant 50 mV applied; pH lowered with 1.0 M HClO4 to 8.5 and raised with 1.0 M KOH to 12.9

Atmosphere
N2
Geometry
gold interdigitated electrode
Context
pristine conductive MOF film
Measurement source
S7 · Chemiresistive measurement · Figure S4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Conductance recovery on restoring basic pHapproximately 63% of the conductance was recovered—approximatelyText
Approximate		S26 · Supplementary Notes · Figure S4
Resistance trend with decreasing pHresistance increased as pH was lowered to 8.5——Text
Qualitative		S26 · Supplementary Notes · Figure S4