Niu L., Zeng L., Yu D. et al. · ACS Nano · 2025 · 2581-2590
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The anion contribution to capacitance drops strongly as rate increases, while the cation contribution remains comparatively stable.
Caveat: Percentages are extracted from the plotted stacked bars and text summary, not from an accompanying table.
2584 · Results and Discussion · Figure 2i · Linked to 4 structured results
The Ni3(HITP)2 film is sufficiently rigid and uniform for Sauerbrey-based EQCM gravimetry.
Caveat: Rigidity evidence is qualitative from SI frequency/dissipation plots; no numeric dissipation threshold is reported in text.
2587 · Methods - EQCM Measurements · Figure S2 · Linked to 3 structured results
EQCM experiments and MD simulations agree on mass-change and cation/anion population trends as charging rate changes.
Caveat: The authors state experimental and simulation charging rates are not exactly the same, but use scaling analysis to justify comparison.
2586 · Conclusions and Perspective · Linked to 3 structured results
Rate-dependent overscreening strength in c-MOF pores explains why anomalous cation accumulation appears in slow charging and disappears at higher charging rates.
Caveat: Mechanism relies primarily on MD radial density and charge-density analysis.
2586 · Conclusions and Perspective · Figures 3 and 4 · Linked to 3 structured results
Increasing charging rate drives a transition from anion-dominated adsorption/desorption to ion-exchange-dominated charging in Ni3(HITP)2/[EMIM][BF4].
Caveat: Directly demonstrated for this electrode-electrolyte pair; authors call for studies across more systems.
2586 · Conclusions and Perspective · Figure 2 · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2Browse family: Ni₃(HITP)₂ / Ni–HITP | Ni3(HITP)2Ni · 2,3,6,7,10,11-hexaiminotriphenylene (HITP) | 2D · PristineConductive metal-organic framework electrode with monodispersed nanopores; atomistic electrode structure used for MD was obtained from experimental measurements reported in prior work. | 2582 · Introduction |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Ni3(HITP)2 c-MOF film working electrode on Au-coated quartzresearch_0827__mat__mat_ni3_hitp2 | Electrode · Target Sample · Pristine Framework | Vacuum filtration and wet-transfer film; NMP temporary adhesive; cellulose membrane dissolved in acetone; vacuum oven at 80 deg C for 3 h.Au-coated quartz sensor | 2587 · Methods - EQCM Measurements · Figure 1a |
| MD model of Ni3(HITP)2 electrodes in [EMIM][BF4]research_0827__mat__mat_ni3_hitp2 | Model · Model System · Model | Simulation box with two Ni3(HITP)2 electrodes immersed in coarse-grained [EMIM][BF4] ionic liquid electrolyte. | 2587 · Methods - Molecular Dynamics Simulations · Figure 1b |
| Ni3(HITP)2 c-MOF powderresearch_0827__mat__mat_ni3_hitp2 | Powder · Target Sample · Pristine Framework | Black precipitate after centrifugation, solvent exchange with water and methanol, filtration and vacuum treatment. | 2587 · Methods - Synthesis of c-MOFs |
| Ni3(HITP)2 c-MOF film on silicon wafer for SEMresearch_0827__mat__mat_ni3_hitp2 | Thin Film · Target Sample · Pristine Framework | Transferred to silicon wafer by the same VFT method.silicon wafer | 2587 · Methods - Characterization of c-MOF Film · Figure S2 |
| Ni3(HITP)2 c-MOF TEM dispersionresearch_0827__mat__mat_ni3_hitp2 | Powder · Target Sample · Pristine Framework | Sample dispersed in acetone; droplet transferred to carbon-coated copper grid.carbon-coated copper grid | 2587 · Methods - Characterization of c-MOF Film · Figure S16a |