Electrical Transport — Two Dual-Function Zr/Hf-MOFs as High-Performance Proton Conductors and Amines Impedance Sensors

6 measurement groups · 114 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Arrhenius activation energy from conductivity

Electrical conductivity

DUT-67(Hf) pressed pellet with platinum electrodes · Pellet

Ea fitted from temperature-dependent proton conductivity at 68% and 98% RH

Atmosphere: humidified H2O
Geometry: pressed pellet
Context: pristine
Measurement source: 3040-3041 · Results and Discussion - Proton Conduction · Figure 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DUT-67(Hf) proton-conduction Ea at 98% RH	0.27 eV	—	—	Text Exact Reported	3040 · Proton Conduction · Figure 5
DUT-67(Hf) proton-conduction Ea at 68% RH	0.73 eV	—	—	Text Exact Reported	3040 · Proton Conduction · Figure 5

Arrhenius activation energy from conductivity

Electrical conductivity

DUT-67(Zr) pressed pellet with platinum electrodes · Pellet

Ea fitted from temperature-dependent proton conductivity at 68% and 98% RH

Atmosphere: humidified H2O
Geometry: pressed pellet
Context: pristine
Measurement source: 3040-3041 · Results and Discussion - Proton Conduction · Figure 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DUT-67(Zr) proton-conduction Ea at 98% RH	0.25 eV	—	—	Text Exact Reported	3040 · Proton Conduction · Figure 5
DUT-67(Zr) proton-conduction Ea at 68% RH	0.75 eV	—	—	Text Exact Reported	3040 · Proton Conduction · Figure 5

AC impedance proton conductivity

Electrical conductivity Impedance spectroscopy

DUT-67(Hf) pressed pellet with platinum electrodes · Pellet

30-100 deg C, 68/75/85/93/98% RH and 98% RH-D2O; 100 mV, 1-10^6 Hz; quasi-four-probe

Temperature: 303.15-373.15
Atmosphere: humidified H2O or D2O atmosphere
Geometry: pressed pellet with platinum electrodes
Context: pristine
Measurement source: 3037 · Experimental Section - Proton Conductivity Test · Equation 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DUT-67(Hf) proton conductivity at 30 deg C, 68% RH	1.31e-07 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 30 deg C, 75% RH	1.42e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 30 deg C, 85% RH	2.21e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 30 deg C, 93% RH	3.35e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 30 deg C, 98% RH	0.000694 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 30 deg C, 98% RH-D2O	0.000183 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 40 deg C, 68% RH	4.32e-07 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 40 deg C, 75% RH	2.23e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 40 deg C, 85% RH	2.61e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 40 deg C, 93% RH	5.77e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 40 deg C, 98% RH	0.000759 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 40 deg C, 98% RH-D2O	0.000204 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 50 deg C, 68% RH	7.47e-07 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 50 deg C, 75% RH	4.81e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 50 deg C, 85% RH	6.91e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 50 deg C, 93% RH	8.1e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 50 deg C, 98% RH	0.000881 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 50 deg C, 98% RH-D2O	0.000249 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 60 deg C, 68% RH	1.43e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 60 deg C, 75% RH	9.11e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 60 deg C, 85% RH	1.23e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 60 deg C, 93% RH	1.73e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 60 deg C, 98% RH	0.00109 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 60 deg C, 98% RH-D2O	0.000305 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 70 deg C, 68% RH	2.31e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 70 deg C, 75% RH	1.16e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 70 deg C, 85% RH	2.52e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 70 deg C, 93% RH	2.79e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 70 deg C, 98% RH	0.00129 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 70 deg C, 98% RH-D2O	0.000387 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 80 deg C, 68% RH	5.21e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 80 deg C, 75% RH	2.3e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 80 deg C, 85% RH	4.25e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 80 deg C, 93% RH	7.81e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 80 deg C, 98% RH	0.00208 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 80 deg C, 98% RH-D2O	0.000455 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 90 deg C, 68% RH	1.94e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 90 deg C, 75% RH	5.59e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 90 deg C, 85% RH	7.82e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 90 deg C, 93% RH	0.000167 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 90 deg C, 98% RH	0.00278 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 90 deg C, 98% RH-D2O	0.000554 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 100 deg C, 68% RH	3.42e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 100 deg C, 75% RH	8.78e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 100 deg C, 85% RH	0.000196 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 100 deg C, 93% RH	0.000496 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 100 deg C, 98% RHMarked as a best value within this paper	0.00386 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
DUT-67(Hf) proton conductivity at 100 deg C, 98% RH-D2O	0.000822 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S2 · Table S2
Table 1 comparison entry for DUT-67(Hf)Marked as a best value within this paper	3.86 x 10^-3 S cm^-1; Table 1 condition appears as 50 deg C and 98% RH	—	—	Table Exact Reported	3040 · Table 1 · Table 1

AC impedance proton conductivity

Electrical conductivity Impedance spectroscopy

DUT-67(Zr) pressed pellet with platinum electrodes · Pellet

30-100 deg C, 68/75/85/93/98% RH and 98% RH-D2O; 100 mV, 1-10^6 Hz; quasi-four-probe

Temperature: 303.15-373.15
Atmosphere: humidified H2O or D2O atmosphere
Geometry: pressed pellet with platinum electrodes
Context: pristine
Measurement source: 3037 · Experimental Section - Proton Conductivity Test · Equation 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DUT-67(Zr) proton conductivity at 30 deg C, 68% RH	1.52e-07 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 30 deg C, 75% RH	2.75e-07 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 30 deg C, 85% RH	5.45e-07 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 30 deg C, 93% RH	9.26e-07 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 30 deg C, 98% RH	0.000441 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 30 deg C, 98% RH-D2O	0.000132 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 40 deg C, 68% RH	6.55e-07 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 40 deg C, 75% RH	1e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 40 deg C, 85% RH	1.26e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 40 deg C, 93% RH	1.7e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 40 deg C, 98% RH	0.000478 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 40 deg C, 98% RH-D2O	0.000197 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 50 deg C, 68% RH	2.46e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 50 deg C, 75% RH	3.1e-07 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 50 deg C, 85% RH	3.96e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 50 deg C, 93% RH	4.86e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 50 deg C, 98% RH	0.000529 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 50 deg C, 98% RH-D2O	0.000214 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 60 deg C, 68% RH	4.05e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 60 deg C, 75% RH	5.53e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 60 deg C, 85% RH	8.21e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 60 deg C, 93% RH	1.03e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 60 deg C, 98% RH	0.000634 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 60 deg C, 98% RH-D2O	0.000252 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 70 deg C, 68% RH	5.21e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 70 deg C, 75% RH	8.12e-06 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 70 deg C, 85% RH	1.39e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 70 deg C, 93% RH	1.92e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 70 deg C, 98% RH	0.000739 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 70 deg C, 98% RH-D2O	0.000321 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 80 deg C, 68% RH	1.13e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 80 deg C, 75% RH	1.71e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 80 deg C, 85% RH	2.57e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 80 deg C, 93% RH	3.1e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 80 deg C, 98% RH	0.000806 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 80 deg C, 98% RH-D2O	0.000373 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 90 deg C, 68% RH	2.22e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 90 deg C, 75% RH	3.22e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 90 deg C, 85% RH	4.72e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 90 deg C, 93% RH	5.4e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 90 deg C, 98% RH	0.00116 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 90 deg C, 98% RH-D2O	0.000643 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 100 deg C, 68% RH	4.9e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 100 deg C, 75% RH	7.96e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 100 deg C, 85% RH	9.74e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 100 deg C, 93% RH	2.12e-05 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 100 deg C, 98% RHMarked as a best value within this paper	0.00298 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
DUT-67(Zr) proton conductivity at 100 deg C, 98% RH-D2O	0.00136 S cm^-1	—	—	SI Table Exact Reported	SI p002 · Table S1 · Table S1
Table 1 comparison entry for DUT-67(Zr)Marked as a best value within this paper	2.98 x 10^-3 S cm^-1 at 100 deg C and 98% RH	—	—	Table Exact Reported	3040 · Table 1 · Table 1

Arrhenius Ea under amine vapours

DUT-67(Hf) impedance gas-sensing pellet between Pt mesh electrodes · Electrode

Ea values toward MA/DMA/TMA at 68% and 98% RH

Atmosphere: humidified amine vapour
Geometry: gas-sensing impedance cell
Context: pristine
Measurement source: 3043-3044 · Results and Discussion - Sensing Properties · Figure 9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DUT-67(Hf) sensing Ea toward MA at 98% RH	0.24 eV	—	—	Figure Axis Rounded Reported	3042-3043 · Sensing Properties · Figure 9
DUT-67(Hf) sensing Ea toward DMA at 98% RH	0.26 eV	—	—	Figure Axis Rounded Reported	3042-3043 · Sensing Properties · Figure 9
DUT-67(Hf) sensing Ea toward TMA at 98% RH	0.27 eV	—	—	Figure Axis Rounded Reported	3042-3043 · Sensing Properties · Figure 9
DUT-67(Hf) sensing Ea toward MA at 68% RH	0.55 eV	—	—	Text Exact Reported	3042-3043 · Sensing Properties · Figure 9
DUT-67(Hf) sensing Ea toward DMA at 68% RH	0.67 eV	—	—	Text Exact Reported	3042-3043 · Sensing Properties · Figure 9
DUT-67(Hf) sensing Ea toward TMA at 68% RH	0.68 eV	—	—	Text Exact Reported	3042-3043 · Sensing Properties · Figure 9

Arrhenius Ea under amine vapours

DUT-67(Zr) impedance gas-sensing pellet between Pt mesh electrodes · Electrode

Ea values toward MA/DMA/TMA at 68% and 98% RH

Atmosphere: humidified amine vapour
Geometry: gas-sensing impedance cell
Context: pristine
Measurement source: 3042-3043 · Results and Discussion - Sensing Properties · Figures 8-9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DUT-67(Zr) sensing Ea toward MA at 98% RH	0.29 eV	—	—	Figure Axis Rounded Reported	3042-3043 · Sensing Properties · Figure 8
DUT-67(Zr) sensing Ea toward DMA at 98% RH	0.31 eV	—	—	Figure Axis Rounded Reported	3042-3043 · Sensing Properties · Figure 8
DUT-67(Zr) sensing Ea toward TMA at 98% RH	0.33 eV	—	—	Figure Axis Rounded Reported	3042-3043 · Sensing Properties · Figure 8
DUT-67(Zr) sensing Ea toward MA at 68% RH	0.52 eV	—	—	Text Exact Reported	3042-3043 · Sensing Properties · Figure 8
DUT-67(Zr) sensing Ea toward DMA at 68% RH	0.53 eV	—	—	Text Exact Reported	3042-3043 · Sensing Properties · Figure 8
DUT-67(Zr) sensing Ea toward TMA at 68% RH	0.55 eV	—	—	Text Exact Reported	3042-3043 · Sensing Properties · Figure 8