Spectroscopy — 1D Conductive Metal-Organic Framework-Enabled Dual-Parameter MEMS Gas Sensor for Thermal Runaway Monitoring

5 measurement groups · 19 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

In-situ grown CuBTA film on MEMS IDEs · Thin Film

Exposure to 1% CO for 5 min, then N2 purge

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Gas-phase/adsorbed CO band	about 2120 cm^-1	—	—	Text Approximate	p.7 · Results and Discussion, 2.3 · Figure 5b,c
CO R-branch band	2217 cm^-1	—	—	Text Exact Reported	p.7 · Results and Discussion, 2.3 · Figure 5b,c
CuBTA adsorbed CO band	2125 cm^-1	—	—	Text Exact Reported	p.7 · Results and Discussion, 2.3 · Figure 5b,c

In-situ grown NiBTA film on MEMS IDEs · Thin Film

Exposure to 1% CO for 5 min, then N2 purge

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NiBTA adsorbed CO band	2123 cm^-1	—	—	Text Exact Reported	p.7 · Results and Discussion, 2.3 · Figure 5b,c

CuBTA powder · Powder

Raman with 532 nm excitation; FTIR spectra used for C=N, C-N, M-N and N-H bands; MBTA family values reported

Context: Pristine MBTA powder family; result applies to both CuBTA and NiBTA
Measurement source: p.4 · Results and Discussion, 2.1 · Figure 2k,l

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR C=N peak	FTIR C=N peak at 1627 cm^-1	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
FTIR C-N peak	FTIR C-N peak at 1420 cm^-1	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
FTIR N-H peak around 3250 cm^-1	FTIR N-H peak around 3250 cm^-1	—	—	Text Approximate	p.4 · Results and Discussion, 2.1 · Figure 2i-l
Raman C=N peak	Raman C=N peak at 1515 cm^-1	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
Raman C-N peak	Raman C-N peak at 1204 cm^-1	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
Raman M-N band	610-620 cm^-1	—	—	Text Range	p.4 · Results and Discussion, 2.1 · Figure 2k

CuBTA powder · Powder

High-resolution Cu 2p and N 1s spectra

Context: Pristine CuBTA powder
Measurement source: p.4 · Results and Discussion, 2.1 · Figure 2i,j; Figures S3-S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu(II) 2p1/2	Cu(II) 2p1/2 at 955.4 eV	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
Cu(II) 2p3/2	Cu(II) 2p3/2 at 935.6 eV	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
Cu(I) 2p1/2	Cu(I) 2p1/2 at 953.5 eV	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
Cu(I) 2p3/2	Cu(I) 2p3/2 at 933.7 eV	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
N 1s C-N	N 1s C-N at 400.32 eV	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
N 1s C=N-M	N 1s C=N-M at 398.9 eV	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
N 1s N-H	N 1s N-H at 401.5 eV	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l

NiBTA powder · Powder

High-resolution Ni 2p and N 1s spectra

Context: Pristine NiBTA powder
Measurement source: p.4 · Results and Discussion, 2.1 · Figure 2i,j; Figures S3-S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni(II) 2p1/2	Ni(II) 2p1/2 at 873.3 eV	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l
Ni(II) 2p3/2	Ni(II) 2p3/2 at 855.9 eV	—	—	Text Exact Reported	p.4 · Results and Discussion, 2.1 · Figure 2i-l