Zhao J., Zhang T., Ren J. et al. · Chemical Communications · 2023 · 2978-2981
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The combination of acid stability, moderate conductivity, nanochannels and redox-active sites enables high supercapacitor performance in acidic electrolyte.
Caveat: Application measurements are on composite electrodes containing conductive carbon and Nafion; pristine-framework transport is separately measured on pellets.
p004 · Summary · Linked to 6 structured results
Cu-TBC is assigned as a crystalline 2D conductive MOF with AA stacking and P6 symmetry.
Caveat: Structure is based on PXRD/Pawley refinement, simulation and TEM lattice fringes; no CIF/main single-crystal structure provided in the assigned files.
p002 · Structure characterisation · Fig. 1 · Linked to 5 structured results
Cu-TBC behaves as a moderately conductive semiconductor-like framework over 298-360 K.
Caveat: Conductivity was measured by two-probe pellet geometry; contact resistance may contribute. Temperature-dependent values are mostly graphical.
p003 · Electrical properties · Fig. S8 · Linked to 3 structured results
The proposed reversible redox process during charge/discharge is ligand-centred on hydroxyl groups rather than a Cu valence-state change.
Caveat: The paper describes this as inferred from comparison with 6OH-TBC and absence of new Cu-TBC redox peaks; direct operando valence evidence is not reported in the assigned text.
S21 · Section 13 · Scheme S2 · Linked to 2 structured results
Charge storage in the Cu-TBC electrode combines electric-double-layer and pseudocapacitive contributions, with pseudocapacitance dominant.
Caveat: Contribution analysis depends on Trasatti/Dunn assumptions and CV-derived fitting.
p003 · Charge-storage analysis · Fig. 3 · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| 6OH-TBC ligand | C36H18O6none · hexahydroxyl tribenzocoronene | 0D · Model SystemOrganic ligand and electrochemical control; not a MOF | S7 · Section 2. Synthetic Procedures · Scheme S1 |
| Cu-TBC | {C72H24Cu3O12}n; also written as Cu3(6O-TBC)2Cu2+ nodes from bis(1,1,1-trifluoropentane-2,4-dionato-O,O')copper · hexahydroxyl tribenzocoronene (6OH-TBC) | 2D · Pristine2D conductive MOF, AA-stacking model, P6 space group from Pawley refinement / structural simulation | p001 · Abstract/introduction |
| Cu-TBC//AC asymmetric device | Cu-TBC anode // activated carbon cathode with 0.1 M H2SO4 electrolyteCu in Cu-TBC anode · 6OH-TBC-derived Cu-TBC anode; activated carbon cathode | unknown · CompositeTwo-electrode asymmetric supercapacitor device containing Cu-TBC composite electrode | p003 · Electrochemical performance · Fig. 4 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| 6OH-TBC ligand control electroderesearch_0840__mat__mat_6oh_tbc | Electrode · Pristine Control · Composite | ligand investigated electrochemically for comparison with Cu-TBCelectrochemical electrode, details not separately specified for ligand control | S20 · Section 13. Proposed Redox Mechanism · Fig. S14 |
| AA-stacking structural model of Cu-TBCresearch_0840__mat__mat_cutbc | Model · Model System · Model | Forcite / Material Studio model fitted to PXRD | S25 · Section 16. Atomic Coordinates · Table S9 |
| two-electrode asymmetrical Cu-TBC//AC deviceresearch_0840__mat__mat_cutbc_ac_device | Electrode · Composite Sample · Composite | assembled two-electrode device with 50 uL 0.1 M H2SO4 electrolyteCu-TBC-loaded titanium mesh anode; AC-loaded titanium mesh cathode; NKK-MPF30AC-100 separator · Cu-TBC active mass approx. 0.53 mg cm-2; AC active mass approx. 5.3 mg cm-2 | S9-S10 · Section 3. Preparation of Two-electrode Asymmetrical MOF//AC device |
| Cu-TBC modified glassy carbon electroderesearch_0840__mat__mat_cutbc | Electrode · Target Sample · Composite | Cu-TBC/carbon black/Nafion slurry drop-cast and air dried 1 hglassy carbon electrode, area 0.07 cm2 · MOF loading 1.14 mg cm-2 | S9 · Section 3. Standard three-electrode system measurements |
| pressed Cu-TBC pelletresearch_0840__mat__mat_cutbc | Pellet · Target Sample · Pristine Framework | pressed pellet for two-probe conductivitygold wires attached with silver colloid | p002 · Electrical properties · Fig. S8 |
| as-prepared Cu-TBC black powderresearch_0840__mat__mat_cutbc | Powder · Target Sample · Pristine Framework | solvothermally prepared, filtered, washed with DMAc/MeOH/acetone and vacuum dried | S8 · Section 2. Preparation of Cu-TBC |
| Cu-TBC film electrode on titanium meshresearch_0840__mat__mat_cutbc | Electrode · Composite Component · Composite | Cu-TBC/carbon black/Nafion slurry spread on Ti mesh and dried at 80 degC under vacuum overnightround titanium mesh electrode, r = 0.6 cm · active mass approximately 0.53 mg cm-2 in device | S9 · Section 3. Preparation of the MOF and AC film electrode |