Spectroscopy — A tribenzocoronene-based 2D conductive metal-organic framework for efficient energy storage

3 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-prepared Cu-TBC black powder · Powder

C,H by elemental analysis; Cu by ICP-MS / ICP emission spectroscopy

Geometry: powder
Context: pristine framework
Measurement source: S12 · Section 6. Elemental Analysis and ICP-MS · Tables S3-S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Found C content	Found C = 69.86 wt%	—	—	SI Table Exact Reported	S12 · Section 6 · Table S3
Found H content	Found H = 2.80 wt%	—	—	SI Table Exact Reported	S12 · Section 6 · Table S3
Found Cu content	Found Cu = 14.20 wt%	—	—	SI Table Exact Reported	S12 · Section 6 · Table S4

as-prepared Cu-TBC black powder · Powder

Reflection mode, 400-4000 cm-1; comparison of Cu-TBC and 6OH-TBC

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
O-H stretch attenuation after coordination	O-H stretching vibration around 3300 cm-1 belonging to 6OH-TBC was significantly attenuated in Cu-TBC	—	—	Text Approximate	p002 · Composition characterisation · Fig. S3

as-prepared Cu-TBC black powder · Powder

Thermo Scientific K-Alpha, Al Kalpha radiation; C 1s referenced to 284.8 eV

Atmosphere: high vacuum
Geometry: powder
Context: pristine framework
Measurement source: S11 · Section 5. X-Ray Photoelectron Spectroscopy Analysis · Fig. S4; Tables S1-S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu 2p3/2 Cu2+ peak position	Cu (2p2/3)-1 at 934.86 eV; area 96.81%	—	—	SI Table Exact Reported	S11 · Section 5 · Table S1
Cu 2p3/2 Cu+ trace peak position	Cu (2p2/3)-2 at 933.08 eV; area 3.19%	—	—	SI Table Exact Reported	S11 · Section 5 · Table S1
XPS detected elements	only C, O and Cu elements were present	—	—	Text Qualitative	p002 · Composition characterisation · Fig. S4
O 1s-1 peak position	O (1s)-1 at 532.99 eV; area 64.37%	—	—	SI Table Exact Reported	S11 · Section 5 · Table S2
O 1s-2 peak position	O (1s)-2 at 531.60 eV; area 35.63%	—	—	SI Table Exact Reported	S11 · Section 5 · Table S2