Liu X., Yu M., Liu J. et al. · Small · 2024 · 2306159
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Ni-DBH shows the strongest long-cycle Li-ion stability after voltage-window optimisation.
Caveat: This claim is based on the adjusted 1.5-3.2 V window, not the common 1.5-3.5 V 0.5 C comparison.
p006 · Results and Discussion 2.2 · Figure 4e · Linked to 2 structured results
S@Mn-DBH has the best Li-S capacity maintenance and catalytic activity among the three sulfur-loaded electrodes.
Caveat: Best performance depends on metric: Co has faster diffusion and higher restored rate capacity, while Mn has lower Delta E and stronger long-cycle capacity maintenance.
p008-p009 · Results and Discussion 2.3 / Conclusion · Figure 6; Table 1 · Linked to 4 structured results
Layered porosity is proposed to provide uniform sulfur distribution and a physical barrier for polysulfide transport during Li-S cycling.
Caveat: The barrier role is inferred from electrochemical behaviour and porosity, not directly measured polysulfide transport.
p009 · Results and Discussion 2.4 · Linked to 4 structured results
The triptycene-based 3D molecular extension and AB-staggered stacking provide more accessible MO4 active sites for electrolyte contact.
Caveat: The direct comparison to planar 2D c-MOFs is literature-based rather than a same-paper synthetic control.
p009 · Conclusion · Linked to 3 structured results
S@Co-DBH promotes soluble polysulfide migration and has the fastest Li-ion diffusion rate among the sulfur-loaded electrodes.
Caveat: Diffusion coefficients are calculated from CV slopes using the Randles-Sevcik equation; one reduction-stage value is read from the figure.
p006 · Results and Discussion 2.3 · Figure 6a · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Co-DBH | C40O12Co3 (simulation formula)Co(II)-O coordination units · 6OH-DBH | 2D · Pristine2D conductive MOF analogue of M-DBH; AB-staggered stacking inferred from PXRD/HRTEM/SAED. | p004 · Results and Discussion 2.1 · Figure 3 |
| M-DBH family (M = Ni, Co, Mn) | C40O12M3 from structural simulation; M = Ni, Co, or MnDivalent Ni, Co, or Mn centres coordinated by O-functional groups in MO4 units · 9,10-dihydro-9,10-[1,2]benzenoanthracene-2,3,6,7,14,15-hexaol (6OH-DBH) | 2D · PristineTriptycene-based 2D conductive MOFs with 3D molecular extension; AB-staggered stacking best matches PXRD. | p001-p002 · Abstract / Results and Discussion 2.1 · Figure 1 |
| Mn-DBH | C40O12Mn3 (simulation formula)Mn(II)-O coordination units · 6OH-DBH | 2D · Pristine2D conductive MOF analogue of M-DBH; AB-staggered stacking and flower-like morphology emphasised. | p004 · Results and Discussion 2.1 · Figure 3 |
| Ni-DBH | C40O12Ni3 (simulation formula)Ni(II)-O coordination units · 6OH-DBH | 2D · Pristine2D honeycomb lattice with AB-staggered stacking; flower-like and flake morphologies observed. | p002 · Results and Discussion 2.1 · Figure 1 |
| S@Co-DBH | Sulfur-loaded Co-DBH composite, M-DBH:sulfur = 3:7 by weight in preparationCo(II)-O units of Co-DBH host · 6OH-DBH framework with sulfur guest/composite phase | 2D · CompositeSulfurized 2D c-MOF composite used as Li-S cathode active material. | p006 · Results and Discussion 2.3 · Figure 6 |
| S@Mn-DBH | Sulfur-loaded Mn-DBH composite, M-DBH:sulfur = 3:7 by weight in preparationMn(II)-O units of Mn-DBH host · 6OH-DBH framework with sulfur guest/composite phase | 2D · CompositeSulfurized 2D c-MOF composite used as Li-S cathode active material. | p008-p009 · Results and Discussion 2.3 / Conclusion · Figure 6, Table 1 |
| S@Ni-DBH | Sulfur-loaded Ni-DBH composite, M-DBH:sulfur = 3:7 by weight in preparationNi(II)-O units of Ni-DBH host · 6OH-DBH framework with sulfur guest/composite phase | 2D · CompositeSulfurized 2D c-MOF composite used as Li-S cathode active material. | p003 · 2.2 Preparation of S@ M-DBH |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Co-DBH pristine powderresearch_0852__mat__co_dbh | Powder · Pristine Control · Pristine Framework | As-synthesised black product from Co acetate and 6OH-DBH. | p003 · 2.1 Preparation of M-DBH |
| Pressed M-DBH conductivity films with evaporated Auresearch_0852__mat__m_dbh_family | Thin Film · Target Sample · Pristine Framework | Pressed at 8 MPa for 3-4 times; thin Au layer evaporated onto glass; measured at 298 K.Glass substrate with evaporated Au layer · 30 mg sample pressed in 16 mm die; film thickness not reported | p004 · 2.4 The measurement of electrical conductivity |
| M-DBH Li-ion battery electrodesresearch_0852__mat__m_dbh_family | Electrode · Target Sample · Composite | 70 wt.% M-DBH active material, 20 wt.% Super P, 10 wt.% PVDF slurry coated onto aluminium foil and dried at 50 deg C for 24 h.Aluminium foil current collector · loading mass 0.91-1 mg cm^-2 | p004 · 2.5 Electrochemical Characterization |
| Pristine M-DBH powders (M = Ni, Co, Mn)research_0852__mat__m_dbh_family | Powder · Paper Level Unspecified · Pristine Framework | Bottom-up synthesis; washed with water and acetone; dried overnight under vacuum at room temperature. | p003 · 2.1 Preparation of M-DBH |
| M-DBH AA/AA-prime/AB stacking computational modelsresearch_0852__mat__m_dbh_family | Model · Model System · Model | Materials Studio/DFTB+ structural models based on C40O12M3 molecular model and 4 x 4 x 2 supercell. | p005 · 3. Structure Simulation · Figure S1 |
| Mn-DBH pristine powderresearch_0852__mat__mn_dbh | Powder · Pristine Control · Pristine Framework | As-synthesised black product from Mn acetate and 6OH-DBH. | p003 · 2.1 Preparation of M-DBH |
| Ni-DBH pristine powderresearch_0852__mat__ni_dbh | Powder · Pristine Control · Pristine Framework | As-synthesised black product from Ni acetate and 6OH-DBH. | p002 · Results and Discussion 2.1 · Figure 1 |
| S@M-DBH Li-S battery electrodesresearch_0852__mat__m_dbh_family | Electrode · Composite Sample · Composite | 70 wt.% S@M-DBH active material, 20 wt.% Super P, 10 wt.% PVDF slurry coated onto aluminium foil and dried at 50 deg C for 24 h.Aluminium foil current collector · loading mass 0.91-1 mg cm^-2 | p006 · Results and Discussion 2.3 · Figure 5 |
| Sulfur-loaded S@M-DBH powders (M = Ni, Co, Mn)research_0852__mat__m_dbh_family | Powder · Composite Sample · Composite | M-DBH powder coheated with sublimed sulfur after dry ball milling; final composite ball-milled again. | p003 · 2.2 Preparation of S@ M-DBH |